bis(2-chlorobenzyl)amine

Base Information

• Chemical Name: bis(2-chlorobenzyl)amine
• CAS No.: 65130-79-2
• Molecular Formula: C₁₄H₁₃Cl₂N
• Molecular Weight: 266.17
• Mol file: 65130-79-2.mol

Synonyms:bis(2-chlorobenzyl)amine

Chemical Property of bis(2-chlorobenzyl)amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(2-chlorobenzyl)amine

There total 14 articles about bis(2-chlorobenzyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2-CHLOROBENZYLAMINE (89-97-4) → bis(2-chlorobenzyl)amine (65130-79-2)

Guidance literature:

With γ-Al2O3 supported Pt-Sn; In o-xylene; at 145 ℃; for 24h; under 750.075 Torr; Inert atmosphere;

DOI:10.1002/chem.201101725

Reference yield: 92.0%

2-Chlorobenzonitrile (873-32-5) → bis(2-chlorobenzyl)amine (65130-79-2)

Guidance literature:

With borane-ammonia complex; C₁₆H₂₉Cl₂CoN₂P; at 25 ℃; for 13h; chemoselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.201608345

Reference yield: 92.0%

→ bis(2-chlorobenzyl)amine (65130-79-2)

Guidance literature:

With borane-ammonia complex; C₁₆H₂₉Cl₂CoN₂P; at 25 ℃; for 13h; Inert atmosphere; Schlenk technique;

upstream raw materials:

2-Chlorobenzonitrile

2-chloro-benzaldehyde

ethanol

(E)-2-chlorobenzaldehyde oxime

Downstream raw materials:

N-(2-chlorobenzylidene)-1-(2-chlorophenyl)methylamine

Refernces

• 1、 Jin, Sen,Wang, Hui,Li, Lei,Luo, Xiao,Sun, Xianshun,Zuo, Ming,Tian, Jie,Zhang, Xiaodong,Xie, Yi. "Surface modification boosts exciton extraction in confined layered structure for selective oxidation reaction". . p. 1964 - 1969. Retrieved 2021/10/25.
• 2、 -. "Cobalt complex, preparation method thereof, and application thereof in selective catalysis of transfer hydrogenation reaction of cyano group". Paragraph 0165-0167; 0169. . Retrieved 2018/05/07.