2-Methylfuran-3-carbaldehyde

Base Information

• Chemical Name: 2-Methylfuran-3-carbaldehyde
• CAS No.: 5612-67-9
• Molecular Formula: C6H6 O2
• Molecular Weight: 110.11064
• Hs Code.: 2932190090
• European Community (EC) Number: 838-864-3
• DSSTox Substance ID: DTXSID70508482
• Nikkaji Number: J1.723.519B
• Wikidata: Q82365440
• Mol file: 5612-67-9.mol

Synonyms:2-methylfuran-3-carbaldehyde;2-Methyl-3-furaldehyde;5612-67-9;3-Formyl-2-methylfuran;3-Furancarboxaldehyde, 2-methyl-;2-Methylfuran-3-carboxaldehyde;2-methylfuran-3-aldehyde;SCHEMBL644095;2-Methyl-furan-3-carbaldehyde;DTXSID70508482;MFCD09702375;AKOS012321617;AT17469;MS-22502;CS-0242623;FT-0649381;EN300-252932;J-510051;Z1079442526

Chemical Property of 2-Methylfuran-3-carbaldehyde

Chemical Property:

• Vapor Pressure: 2.534mmHg at 25°C
• Boiling Point: 159.2°Cat760mmHg
• Flash Point: 56.8°C
• PSA: 30.21000
• Density: 1.099g/cm³
• LogP: 1.40050
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 110.036779430
• Heavy Atom Count: 8
• Complexity: 90.5

Purity/Quality:

98%Min ^*data from raw suppliers

2-methylfuran-3-carbaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(C=CO1)C=O

Technology Process of 2-Methylfuran-3-carbaldehyde

There total 12 articles about 2-Methylfuran-3-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

(2-methylfuran-3-yl)methanol (5554-99-4) → 2-methyl-furan-3-carboxaldehyde (5612-67-9)

Guidance literature:

With tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide; In dichloromethane; at 20 ℃; for 1h; 4A sieves;

Reference yield: 66.0%

1-(3'-furyl)-ethanol (13129-26-5) → 2-methyl-furan-3-carboxaldehyde (5612-67-9)

Guidance literature:

With water; bromine; In acetone; at 0 - 20 ℃;

DOI:10.1002/jccs.200800035

Reference yield: 65.0%

2-Methyl-N-phenyl-furan-3-carboximidoyl chloride (79190-43-5) → 2-methyl-furan-3-carboxaldehyde (5612-67-9)

Guidance literature:

With acid chlorhydrique; chlorure stanneux; In diethyl ether; at 20 ℃; for 18h;

upstream raw materials:

furan-3-carboxaldehyde

methyl iodide

2-methylfuran-3-carbonyl chloride

2-Methyl-N-phenyl-furan-3-carboximidoyl chloride

Downstream raw materials:

N,N'-bis-(2-furancarboxaldimine)-4,5-dimethyl-1,2-phenylenediamine

N,N′-bis-(2-furancarboxaldimine)-4,5-dichloro-1,2-phenylenediamine

dimethyl-2,5 formyl-3 furanne

acide β-(methyl-2 furyl)-3 acrylique

Refernces

• 1、 Harn, Piin-Jye,Lin, Chu-Chung,Wu, Hsien-Jen. "Oxidation of 3-furfurylcarbinols with bromine in acetone-water". experimental part. p. 233 - 238. Retrieved 2009/04/06.
• 2、 -. "FUSED QUINOLINE DERIVATIVE AND USE THEREOF". Page/Page column 110-111. . Retrieved 2008/06/13.