Technology Process of tert-Butylmercuric chloride
There total 4 articles about tert-Butylmercuric chloride which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran; pentane;
at 0 ℃;
for 1h;
Schlenk technique;
DOI:10.1002/anie.201901772
- Guidance literature:
-
In
tetrahydrofuran;
0°C; recrystn. (hexane/EtOH);
- Guidance literature:
-
With
tert.-butyl lithium;
In
tetrahydrofuran; pentane;
under Ar; addn. of t-butyllithium/pentane to soln. of HgCl2 in THF at 0°C with stirring; stirred (1 h, 0°C);; addn. of H2O; filtered by suction in air; concn. to dryness; fractionated between benzene and water; the organic phase was extd. with H2O 5 times, dried (CaCl2), filtered, and evapd. to dryness; crystn. (CH3OH, air, -40°C, dim light); elem. anal.;
