Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide

Base Information

• Chemical Name: Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide
• CAS No.: 86411-02-1
• Molecular Formula: C₁₂H₈O₄S₄
• Molecular Weight: 344.457
• Mol file: 86411-02-1.mol

Synonyms:Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide

Chemical Property of Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide

There total 3 articles about Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

→ 2,2'-Dithiobis(benzenesulfinic acid) (86411-03-2) + Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide (86411-02-1)

Guidance literature:

With hydrazine; In acetonitrile; 1) -10 degC, 30min, 2) warm to room temp.;

DOI:10.1021/jo00166a001

Reference yield: 5.0%

→ benzene-1,2-disulfonic acid (31375-00-5) + 2,2'-disulfanediyl-bis-benzenesulfonic acid (47221-29-4) + Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide (86411-02-1)

Guidance literature:

In acetonitrile; at 55 ℃; for 504h;

DOI:10.1021/jo00166a001

Reference yield:

benzenesulfenyl chloride (931-59-9) → Dibenzo-1,2,5,6-tetrathiocin 1,1,5,5-tetraoxide (86411-02-1) + S,S'-Diphenyl 1,2-benzenedithiosulfonate (86411-15-6) + S,S'-Diphenyl 2,2'-dithiobis(benzenethiosulfonate) (86411-09-8)

Guidance literature:

With sodium sulfite; Yield given. Multistep reaction; 1) Acetonitrile, H₂O, room temp., 2) Ether, 30percent aq. sulfuric acid;

DOI:10.1021/jo00166a001

upstream raw materials:

benzenesulfenyl chloride

Downstream raw materials:

S-Phenyl 2-(tert-butyldithio)benzenethiosulfonate

2-(tert-Butyldithio)phenyl methyl sulfone

Sodium 2-(tert-butyldithio)benzenesulfinate

Tetra-n-butylammonium 2-(tert-butyldithio)benzenesulfinate

Refernces