5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl

Base Information

• Chemical Name: 5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl
• CAS No.: 390366-28-6
• Molecular Formula: C₃₆H₃₄N₄O₂
• Molecular Weight: 554.692
• Mol file: 390366-28-6.mol

Synonyms:5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl

Chemical Property of 5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl

There total 1 articles about 5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

N,N-diethyl-4-iodobenzamide (77350-52-8) + 5,5'-diethynyl-2,2'-bipyridyl (162318-26-5) → 5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl (390366-28-6)

Guidance literature:

With diethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In tetrahydrofuran; at 20 ℃; for 14h;

DOI:10.1021/jp013008j

Reference yield: 50.0%

ammonium hexafluorophosphate + cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3) + 5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl (390366-28-6) → ruthenium(II)(2,2'-bipyridine)2(5,5'-bis[(4-(N,N-diethylcarboxamido)phenyl)ethynyl]-2,2'-bipyridinyl)(PF6)2

Guidance literature:

With AgCF₃SO₃; In acetone; Ru(bpy)2Cl2, AgCF3SO3, and acetone combined in a flask, refluxed for 2 hunder N2, filtered through a medium porosity fritted funnel, concentrat ed, transferred to a flask, 95% EtOH added, refluxed for 17 h under N2, aq. soln. of NH4PF6 added; product precipitated as a brick-red powder, collected by filtration, washed with diethyl ether, purified by column chromy. on alumina eluting with mixtures of CH2Cl2 and CH3CN;

DOI:10.1021/jp013008j

upstream raw materials:

N,N-diethyl-4-iodobenzamide

5,5'-diethynyl-2,2'-bipyridyl

Refernces