3,4,5-tristetradecyloxybenzyl bromide

Base Information

• Chemical Name: 3,4,5-tristetradecyloxybenzyl bromide
• CAS No.: 1228969-38-7
• Molecular Formula: C₄₉H₉₁BrO₃
• Molecular Weight: 808.164
• Mol file: 1228969-38-7.mol

Synonyms:3,4,5-tristetradecyloxybenzyl bromide

Chemical Property of 3,4,5-tristetradecyloxybenzyl bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4,5-tristetradecyloxybenzyl bromide

There total 6 articles about 3,4,5-tristetradecyloxybenzyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[3,4,5-tris(tetradecyloxy)phenyl]methanol (752253-67-1) → 3,4,5-tristetradecyloxybenzyl bromide (1228969-38-7)

Guidance literature:

With pyridine; phosphorus tribromide; In diethyl ether; at -20 ℃;

DOI:10.1055/s-0029-1218684

Reference yield:

1-Bromotetradecane (112-71-0) → 3,4,5-tristetradecyloxybenzyl bromide (1228969-38-7)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium carbonate / N,N-dimethyl-formamide / 6 h / 80 °C / Inert atmosphere

2: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 25 °C / Inert atmosphere

3: phosphorus tribromide / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

With lithium aluminium tetrahydride; phosphorus tribromide; potassium carbonate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/ja209010m

Reference yield:

methyl galloate (99-24-1) → 3,4,5-tristetradecyloxybenzyl bromide (1228969-38-7)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium carbonate / N,N-dimethyl-formamide / 6 h / 80 °C / Inert atmosphere

2: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 25 °C / Inert atmosphere

3: phosphorus tribromide / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

With lithium aluminium tetrahydride; phosphorus tribromide; potassium carbonate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/ja209010m

upstream raw materials:

[3,4,5-tris(tetradecyloxy)phenyl]methanol

1-Bromotetradecane

methyl galloate

methyl [3,4,5-tris(n-tetradecan-1-yloxy)]benzoate

Downstream raw materials:

C₆₀H₁₀₀O₉

Refernces

• 1、 Ichikawa, Takahiro,Yoshio, Masafumi,Hamasaki, Atsushi,Taguchi, Satomi,Liu, Feng,Zeng, Xiang-Bing,Ungar, Goran,Ohno, Hiroyuki,Kato, Takashi. "Induction of thermotropic bicontinuous cubic phases in liquid-crystalline ammonium and phosphonium salts". supporting information; scheme or table. p. 2634 - 2643. Retrieved 2012/03/22.