Tributyl(5,6-dihydro-1,4-dioxin-2-yl)stannane

Base Information

• Chemical Name: Tributyl(5,6-dihydro-1,4-dioxin-2-yl)stannane
• CAS No.: 131470-66-1
• Molecular Formula: C16H32O2Sn
• Molecular Weight: 375.139
• Hs Code.: 2931200000
• European Community (EC) Number: 890-268-2
• DSSTox Substance ID: DTXSID80455231
• Mol file: 131470-66-1.mol

Synonyms:131470-66-1;tributyl(5,6-dihydro-1,4-dioxin-2-yl)stannane;2-(Tributylstannyl)-5,6-dihydro-[1,4]-dioxin;tributyl(2,3-dihydro-1,4-dioxin-5-yl)stannane;Stannane, tributyl(5,6-dihydro-1,4-dioxin-2-yl)-;SCHEMBL238943;DTXSID80455231;TWIASPXZARVBBY-UHFFFAOYSA-N;AKOS015908908;EN300-18574158;tributyl-(5,6-dihydro-[1,4]dioxin-2-yl)-stannane

Chemical Property of Tributyl(5,6-dihydro-1,4-dioxin-2-yl)stannane

Chemical Property:

• Vapor Pressure: 6.94E-05mmHg at 25°C
• Boiling Point: 354.2 °C at 760 mmHg
• Flash Point: 168 °C
• PSA: 18.46000
• LogP: 4.25320
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 376.142433
• Heavy Atom Count: 19
• Complexity: 242

Purity/Quality:

99% ^*data from raw suppliers

2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C1=COCCO1

Technology Process of Tributyl(5,6-dihydro-1,4-dioxin-2-yl)stannane

There total 1 articles about Tributyl(5,6-dihydro-1,4-dioxin-2-yl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1,4-dioxene (543-75-9) + tributyltin chloride (1461-22-9) → tributyl-(5,6-dihydro-[1,4]dioxin-2-yl)stannane (131470-66-1)

Guidance literature:

1,4-dioxene; With tert.-butyl lithium; In diethyl ether; pentane; at -78 - -40 ℃; for 0.5h;

tributyltin chloride; In diethyl ether; pentane; at 10 ℃; for 1h;

DOI:10.1002/anie.201807709

Reference yield: 93.0%

tributyl-(5,6-dihydro-[1,4]dioxin-2-yl)stannane (131470-66-1) + benzoyl chloride (98-88-4) → (5,6-Dihydro-[1,4]dioxin-2-yl)-phenyl-methanone (131470-69-4)

Guidance literature:

trans-benzyl(chloro)bis(triphenylphosphine)palladium(II); In benzene; for 3h; Heating;

DOI:10.1055/s-1990-27005

Reference yield: 93.0%

tributyl-(5,6-dihydro-[1,4]dioxin-2-yl)stannane (131470-66-1) + 4-methoxy-benzoyl chloride (100-07-2) → (5,6-Dihydro-[1,4]dioxin-2-yl)-(4-methoxy-phenyl)-methanone (131470-70-7)

Guidance literature:

trans-benzyl(chloro)bis(triphenylphosphine)palladium(II); In benzene; for 3h; Heating;

DOI:10.1055/s-1990-27005

upstream raw materials:

1,4-dioxene

tributyltin chloride

Downstream raw materials:

(5,6-Dihydro-[1,4]dioxin-2-yl)-phenyl-methanone

(5,6-Dihydro-[1,4]dioxin-2-yl)-(4-methoxy-phenyl)-methanone

(5,6-Dihydro-[1,4]dioxin-2-yl)-(4-nitro-phenyl)-methanone

3-(5,6-Dihydro-[1,4]dioxin-2-yl)-2,2,4-trimethyl-cyclohex-3-enone

Refernces