3-Vinylphenylboronic acid

Base Information

• Chemical Name: 3-Vinylphenylboronic acid
• CAS No.: 15016-43-0
• Molecular Formula: C8H9BO2
• Molecular Weight: 147.969
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID30402437
• Nikkaji Number: J1.632.514G
• Wikidata: Q82205849
• Mol file: 15016-43-0.mol

Synonyms:3-Vinylphenylboronic acid;15016-43-0;(3-Vinylphenyl)boronic acid;(3-ethenylphenyl)boronic Acid;3-Vinylbenzeneboronic acid;3-Vinylphenylbronicacid;Boronic acid, (3-ethenylphenyl)-;Styrene-3-boronic acid;3-Vinylphenylboronic Acid (contains varying amounts of Anhydride);MFCD01074679;3-styryldihydroxyborane;3-Vinylphenylbronic acid;3-vinyl-phenylboronic acid;3-vinylphenyl boronic acid;(3-Vinylphenyl)boronicacid;SCHEMBL397161;DTXSID30402437;SYBQEKBVWDPVJM-UHFFFAOYSA-N;Boronic acid, B-(3-ethenylphenyl)-;AKOS004116594;AB08117;CS-W008465;DS-3679;BP-10486;FT-0616426;V0141;H11855;A809017;J-513127

Chemical Property of 3-Vinylphenylboronic acid

Chemical Property:

• Vapor Pressure: 0.000134mmHg at 25°C
• Melting Point: 127-129°C
• Refractive Index: 1.539
• Boiling Point: 320.2 °C at 760 mmHg
• PKA: 8.34±0.10(Predicted)
• Flash Point: 147.5 °C
• PSA: 40.46000
• Density: 1.09 g/cm³
• LogP: 0.00940
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 148.0695597
• Heavy Atom Count: 11
• Complexity: 136

Purity/Quality:

99% ^*data from raw suppliers

3-Vinylphenylboronic Acid (contains varying amounts of Anhydride) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi, Xn
• Hazard Codes: Xi,Xn
• Statements: 36/37/38-22
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=CC(=CC=C1)C=C)(O)O
• Uses: suzuki reaction Reactant involved in:Suzuki-Miyaura reactionsMolecular imprinting of fructose and pinacolSynthesis of arylmercapturic acids via Chen-Lam-Evans arylationThree-component cross-coupling yeilding diarylketonesGeneration of acyl anion equivalents

Technology Process of 3-Vinylphenylboronic acid

There total 1 articles about 3-Vinylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 3-vinylphenylboronic acid (15016-43-0)

Guidance literature:

3-Vinyl-phenyl-magnesium-bromid, Tributyl-borat in Ae.;

DOI:10.1021/jo01054a071

Reference yield: 98.0%

2,3-dimethyl-2,3-butane diol (76-09-5) + 3-vinylphenylboronic acid (15016-43-0) → 4,4,5,5-tetramethyl-2-(3-vinylphenyl)-1,3,2-dioxaborolane

Guidance literature:

With magnesium sulfate; In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/acs.joc.6b01446

Reference yield: 96.5%

9-Chloroacridine (1207-69-8) + 3-vinylphenylboronic acid (15016-43-0) → C21H15N

Guidance literature:

With sodium carbonate; palladium dichloride; In water; toluene; at 50 ℃; for 4h;

Downstream raw materials:

2-(3-vinyl-phenyl)pyridine

ketoprofen methyl ester

3-benzoylstyrene

ketoprofen