L-Talitol

Base Information

• Chemical Name: L-Talitol
• CAS No.: 60660-58-4
• Molecular Formula: C6H14O6
• Molecular Weight: 182.174
• Hs Code.: 29054990
• UNII: KMN74NT75W,9TD9L8S68N
• DSSTox Substance ID: DTXSID90364289
• Nikkaji Number: J1.581.709G
• Wikidata: Q82148149
• Mol file: 60660-58-4.mol

Synonyms:altritol;D-altritol;L-altritol;talitol

Chemical Property of L-Talitol

Chemical Property:

• Refractive Index: -2 ° (C=1, H2O)
• Boiling Point: 494.9 °C at 760 mmHg
• Flash Point: 292.6 °C
• PSA: 121.38000
• Density: 1.596g/cm³
• LogP: -3.58540
• Storage Temp.: 2-8°C
• Water Solubility.: Soluble in water
• XLogP3: -3.1
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 182.07903816
• Heavy Atom Count: 12
• Complexity: 105

Purity/Quality:

98%, ^*data from raw suppliers

L-Talitol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C(CO)O)O)O)O)O
• Isomeric SMILES: C([C@@H]([C@H]([C@H]([C@H](CO)O)O)O)O)O
• Uses: L-Talitol is a rare sugar alcohol. A laxative.

Technology Process of L-Talitol

There total 76 articles about L-Talitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.2%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + ethylene glycol (107-21-1) + isopropyl alcohol (67-63-0,8013-70-5) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With water; at 220 ℃; for 0.5h; under 52505.3 Torr; Temperature; Pressure;

Reference yield: 33.6%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + isopropyl alcohol (67-63-0,8013-70-5) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With water; at 220 ℃; for 0.5h; under 45004.5 Torr; Temperature; Pressure;

Reference yield: 15.8%

cellulose (9004-34-6) → propylene glycol (57-55-6,63625-56-9) + sorbitol (50-70-4,69-65-8,87-78-5,133-43-7,488-44-8,488-45-9,608-66-2,643-01-6,643-03-8,5552-13-6,6706-59-8,24557-79-7,25878-23-3,26566-34-7,45007-61-2,60660-56-2,60660-57-3,60660-58-4,132747-27-4)

Guidance literature:

With hydrogen; In water; at 239.84 ℃; for 4h; under 30003 Torr;

DOI:10.1039/c2gc35685f

upstream raw materials:

L-altrose

(1S,2S)-1-((4S,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propane-1,2,3-triol

[(2R,3S)-3-((4R,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-oxiranyl]-methanol

(E)-3-((4S,5R)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

Downstream raw materials:

DL-altritol

DL-glucitol hexa-acetate

O¹,O³;O²,O⁴;O⁵,O⁶-trimethanediyl-DL-glucitol

L-Talitol hexaacetate

Refernces

• 1、 Guo, Jiaxing,He, Minyao,Li, Cuiqing,Liu, ShanShan,Song, Yongji,Wang, Hong,Wang, Xincheng. "Direct conversion of cellulose into isosorbide over Ni doped NbOPO4catalysts in water". supporting information. p. 10292 - 10299. Retrieved 2020/07/14.
• 2、 Lucas, Martin,Fabi?ovicová, Katarina,Claus, Peter. "Hydrothermally Stable Ruthenium–Zirconium–Tungsten Catalyst for Cellulose Hydrogenolysis to Polyols". . p. 612 - 618. Retrieved 2017/12/28.