Tributyl(methyl)phosphanium methyl carbonate

Base Information

• Chemical Name: Tributyl(methyl)phosphanium methyl carbonate
• CAS No.: 120256-45-3
• Molecular Formula: C13H30P.C2H3O3
• Molecular Weight: 0
• European Community (EC) Number: 628-961-7
• DSSTox Substance ID: DTXSID80584833
• Mol file: 120256-45-3.mol

Synonyms:120256-45-3;TRIBUTYL(METHYL)PHOSPHANIUM METHYL CARBONATE;methyl carbonate;tributyl(methyl)phosphanium;Tributylmethylphosphonium methyl carbona;Tributylmethylphosphonium methylcarbonate;Methyltributylphosphonium methyl carbonate;SCHEMBL626822;DTXSID80584833;MFCD09265059;AKOS015908465;Tributyl(methyl)phosphonium methyl carbonate;Tributylmethylphosphonium methylcarbonate, 50% in MeOH;Tributylmethylphosphonium methylcarbonate, ~50% in MeOH;Tributylmethylphosphonium 1,1,2,2-tetrafluoroethanesulfonate

Chemical Property of Tributyl(methyl)phosphanium methyl carbonate

Chemical Property:

• Refractive Index: n20/D 1.413
• Flash Point: 50 °C
• PSA: 62.95000
• LogP: 4.01020
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 292.21673191
• Heavy Atom Count: 19
• Complexity: 133

Purity/Quality:

98%Min ^*data from raw suppliers

TRIBUTYLMETHYLPHOSPHONIUM METHYL CARBONATE SOLUTION 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10-20/21/22-36/37/38-39/23/24/25:
• Hazard Codes: T
• Statements: 10-20/21/22-36/37/38-39/23/24/25
• Safety Statements: 26-36/37-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[P+](C)(CCCC)CCCC.COC(=O)[O-]

Technology Process of Tributyl(methyl)phosphanium methyl carbonate

There total 2 articles about Tributyl(methyl)phosphanium methyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

tributylphosphine (998-40-3) + carbonic acid dimethyl ester (616-38-6) → tri-n-butyl(methyl)phosphonium methyl carbonate (120256-45-3)

Guidance literature:

In methanol; at 140 ℃; for 24h; Inert atmosphere; Autoclave;

DOI:10.1039/c0ob00105h

Reference yield:

tributylphosphine (998-40-3) → tri-n-butyl(methyl)phosphonium methyl carbonate (120256-45-3)

Guidance literature:

Reference yield: 100.0%

tri-n-butyl(methyl)phosphonium methyl carbonate (120256-45-3) + p-toluenesulfonic acid monohydrate (6192-52-5) → tributyl(methyl)phosphonium 4-methylbenzenesulfonate (55767-12-9)

Guidance literature:

In methanol; at 40 ℃; for 1h;

DOI:10.1039/c0ob00105h

upstream raw materials:

tributylphosphine

carbonic acid dimethyl ester

Downstream raw materials:

tributyl-methylphosphonium bromide

tributyl(methyl)phosphonium 4-methylbenzenesulfonate

methyltributylphosphonium chloride

tributyl-methyl-phosphonium bis(trifluoromethylsulfonyl)imide

Refernces

• 1、 -. "A method for preparing ionic liquid". Paragraph 0082; 0083. . Retrieved 2018/01/11.
• 2、 -. "Electrochemically stable onium salts and electrolytes containing such for electrochemical capacitors". Page column 10. . Retrieved 2008/06/13.