9-Anthracenylmethyl acrylate

Base Information

• Chemical Name: 9-Anthracenylmethyl acrylate
• CAS No.: 31645-34-8
• Molecular Formula: C18H14O2
• Molecular Weight: 262.308
• Hs Code.: 29161290
• DSSTox Substance ID: DTXSID50398944
• Nikkaji Number: J799.563F
• Wikidata: Q72443494
• Mol file: 31645-34-8.mol

Synonyms:9-Anthracenylmethyl acrylate;31645-34-8;Anthracen-9-ylmethyl Prop-2-enoate;Anthracen-9-ylmethyl acrylate;9-Anthrylmethyl Acrylate;Acrylic Acid 9-Anthrylmethyl Ester;(ANTHRACEN-9-YL)METHYL PROP-2-ENOATE;Anthracen-9-ylmethylacrylate;SCHEMBL68439;DTXSID50398944;IPLSGZRALKDNRS-UHFFFAOYSA-N;9-Anthracenylmethyl acrylate, 98%;MFCD04039960;AKOS015838904;AS-59633;CS-0188288;FT-0653862;E84086;A820939;J-018502

Chemical Property of 9-Anthracenylmethyl acrylate

Chemical Property:

• Vapor Pressure: 1.1E-07mmHg at 25°C
• Melting Point: 86.5-87.5 °C(Solv: ethanol (64-17-5))
• Refractive Index: 1.662
• Boiling Point: 432.6 °C at 760 mmHg
• Flash Point: 284.1 °C
• PSA: 26.30000
• Density: 1.181 g/cm³
• LogP: 4.22220
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 262.099379685
• Heavy Atom Count: 20
• Complexity: 340

Purity/Quality:

99%, ^*data from raw suppliers

9-Anthracenylmethyl acrylate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCC1=C2C=CC=CC2=CC3=CC=CC=C31

Technology Process of 9-Anthracenylmethyl acrylate

There total 3 articles about 9-Anthracenylmethyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

9-hydroxymethylanthracene (1468-95-7) + acryloyl chloride (814-68-6,25189-84-8) → 9-anthracenylmethyl acrylate (31645-34-8)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 1h;

DOI:10.1021/acs.orglett.1c03221

Reference yield: 70.0%

anthracenylmethyl chloride (24463-19-2) + acrylic acid (79-10-7) → 9-anthracenylmethyl acrylate (31645-34-8)

Guidance literature:

acrylic acid; With potassium carbonate; In N,N-dimethyl-formamide; at 0 ℃; for 1h;

anthracenylmethyl chloride; In N,N-dimethyl-formamide; at 100 ℃; for 12h;

DOI:10.1016/j.tet.2018.11.037

Reference yield:

→ 9-anthracenylmethyl acrylate (31645-34-8)

Guidance literature:

9-Chlormethylanthracen, 1.) CH2=CH-COOH, 80-85grad, 2.) CH3CN, (C2H5)3N;

upstream raw materials:

9-hydroxymethylanthracene

acryloyl chloride

anthracenylmethyl chloride

acrylic acid

Refernces

• 1、 Urakami, Hiromitsu,Antonietti, Markus,Vilela, Filipe. "Facile functionalization of HTC-derived carbon microspheres". . p. 10984 - 10986. Retrieved 2012.
• 2、 Odanaka, Yuki,Kanemitsu, Takuya,Iwasaki, Kanako,Mochizuki, Yukiko,Miyazaki, Michiko,Nagata, Kazuhiro,Kato, Masaru,Itoh, Takashi. "Asymmetric Michael addition of malonic diesters to acrylates by phase-transfer catalysis toward the construction of quaternary stereogenic α-carbons". supporting information. p. 209 - 219. Retrieved 2018/12/11.