S-2-bromophenethyl ethanethioate

Base Information

• Chemical Name: S-2-bromophenethyl ethanethioate
• CAS No.: 1103533-46-5
• Molecular Formula: C₁₀H₁₁BrOS
• Molecular Weight: 259.167
• Mol file: 1103533-46-5.mol

Synonyms:S-2-bromophenethyl ethanethioate

Chemical Property of S-2-bromophenethyl ethanethioate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of S-2-bromophenethyl ethanethioate

There total 2 articles about S-2-bromophenethyl ethanethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

2-bromophenylethyl alcohol (1074-16-4) + tiolacetic acid (507-09-5) → S-2-bromophenethyl ethanethioate (1103533-46-5)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2008.08.108

Reference yield: 70.0%

methanesulfonic acid 2-(2-bromophenyl)ethyl ester (2183-83-7) + cesium thioacetate (56827-86-2) → S-2-bromophenethyl ethanethioate (1103533-46-5)

Guidance literature:

In N,N-dimethyl-formamide; at 50 ℃; for 20h; Inert atmosphere;

DOI:10.1016/j.tet.2008.08.108

Reference yield: 91.0%

S-2-bromophenethyl ethanethioate (1103533-46-5) → 2-(2'-bromophenyl)ethanethiol (24084-15-9)

Guidance literature:

With diisobutylaluminium hydride; In diethyl ether; hexane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2008.08.108

upstream raw materials:

2-bromophenylethyl alcohol

tiolacetic acid

methanesulfonic acid 2-(2-bromophenyl)ethyl ester

cesium thioacetate

Downstream raw materials:

2-(2'-bromophenyl)ethanethiol

Refernces