Isopropylidene(3-methylcyclopentadienyl)(9-fluorenyl)zirconium dichloride

Base Information

• Chemical Name: Isopropylidene(3-methylcyclopentadienyl)(9-fluorenyl)zirconium dichloride
• CAS No.: 133190-48-4
• Molecular Formula: C₂₂H₂₀Cl₂Zr
• Molecular Weight: 446.531
• Mol file: 133190-48-4.mol

Synonyms:Zirconium,dichloro[h10-9H-fluoren-9-ylidene(1-methylethylidene)(3-methyl-2,4-cyclopentadien-1-ylidene)]-(9CI); 9H-Fluorene, 9-[1-methyl-1-(3-methyl-1,3-cyclopentadien-1-yl)ethyl]-,zirconium complex;Dimethylmethylene(3-methylcyclopentadienyl)(fluorenyl)zirconium dichloride; Dimethylmethylidene(3-methylcyclopentadienyl)(9-fluorenyl)zirconiumdichloride; Isopropylidene(3-methylcyclopentadienyl)(9-fluorenyl)zirconiumdichloride

Chemical Property of Isopropylidene(3-methylcyclopentadienyl)(9-fluorenyl)zirconium dichloride

Chemical Property:

• PSA: 0.00000
• LogP: 6.32510

Purity/Quality:

98%Min ^*data from raw suppliers

ISOPROPYLIDENE(3-METHYLCYCLOPENTADIENYL)(9-FLUORENYL)ZIRCONIUM DICHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Isopropylidene(3-methylcyclopentadienyl)(9-fluorenyl)zirconium dichloride

There total 1 articles about Isopropylidene(3-methylcyclopentadienyl)(9-fluorenyl)zirconium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

zirconium(IV) chloride (10026-11-6) + 2-(9-fluorenyl)-2-<1-(3-methyl)-1,3-cyclopentadienyl>-propane (216305-06-5) → (η(5)-C5H3Me-CMe2-η(5)-C13H8)ZrCl2 (216852-90-3,133190-48-4)

Guidance literature:

With MeLi; In pentane; inert atmosphere; dropwise addn. of MeLi (in ether) to ligand (in THF), stirring overnight, evapn., suspending in pentane, addn. of metal chloride, stirring for 6 h; decantation, extn. into CH2Cl2, crystn. (-20°C);

DOI:10.1016/0022-328X(95)00115-7

upstream raw materials:

zirconium(IV) chloride

2-(9-fluorenyl)-2-<1-(3-methyl)-1,3-cyclopentadienyl>-propane

Refernces