3-(Phenylmethyl)-2H-azirine

Base Information

• Chemical Name: 3-(Phenylmethyl)-2H-azirine
• CAS No.: 18709-44-9
• Molecular Formula: C₉H₉N
• Molecular Weight: 131.177
• Hs Code.: 2933990090
• Mol file: 18709-44-9.mol

Synonyms:2H-Azirine,3-benzyl- (8CI)

Chemical Property of 3-(Phenylmethyl)-2H-azirine

Chemical Property:

• Boiling Point: 226 ºC
• Flash Point: 82 ºC
• PSA: 12.36000
• Density: 1.05
• LogP: 1.11930
• Storage Temp.: 2-8°C

Purity/Quality:

98%min ^*data from raw suppliers

3-Benzyl-2H-azirine 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(Phenylmethyl)-2H-azirine

There total 1 articles about 3-(Phenylmethyl)-2H-azirine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2-azidoallyl)benzene (28022-22-2) → C9H9N (18709-44-9)

Guidance literature:

In dichloromethane; at 155 ℃; for 0.333333h; Sealed tube;

DOI:10.1021/ol100975b

Reference yield:

C9H9N (18709-44-9) + 4-chlorobenzaldehyde (104-88-1) → C16H14ClNO

Guidance literature:

With 2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; caesium carbonate; In tert-butyl methyl ether; at 25 ℃; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1002/anie.201712785

upstream raw materials:

(2-azidoallyl)benzene

Refernces