N-(4-nitrophenyl)carbamate ion

Base Information

• Chemical Name: N-(4-nitrophenyl)carbamate ion
• CAS No.: 74401-81-3
• Molecular Formula: C₇H₅N₂O₄
• Molecular Weight: 181.128
• Mol file: 74401-81-3.mol

Synonyms:N-(4-nitrophenyl)carbamate ion

Chemical Property of N-(4-nitrophenyl)carbamate ion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of N-(4-nitrophenyl)carbamate ion

There total 4 articles about N-(4-nitrophenyl)carbamate ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4-nitro-phenyl)-carbamic acid-(2,2,2-trifluoro-ethyl ester) (405-59-4) → 2,2,2-trifluoroethanol (75-89-8) + N-(4-nitrophenyl)carbamate ion (74401-81-3)

Guidance literature:

With sodium hydroxide; cetyltrimethylammonim bromide; In 1,4-dioxane; at 26 ℃; Rate constant;

Reference yield:

(4-nitro-phenyl)-carbamic acid-(2-methoxy-ethyl ester) (50882-33-2) → 2-methoxy-ethanol (109-86-4,95507-80-5) + N-(4-nitrophenyl)carbamate ion (74401-81-3)

Guidance literature:

With sodium hydroxide; cetyltrimethylammonim bromide; In 1,4-dioxane; at 26 ℃; Rate constant;

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + 4-nitro-aniline (100-01-6,104810-17-5) → N-(4-nitrophenyl)carbamate ion (74401-81-3)

Guidance literature:

With caesium carbonate; In dimethyl sulfoxide; at 20 ℃; for 1h; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1021/acs.joc.8b00096

upstream raw materials:

methyl N-(4-nitrophenyl)carbamate

(4-nitro-phenyl)-carbamic acid-(2-methoxy-ethyl ester)

(4-nitro-phenyl)-carbamic acid-(2,2,2-trifluoro-ethyl ester)

carbon dioxide

Downstream raw materials:

4-nitro-aniline

Refernces

• 1、 Broxton, Trevor J.. "Micellar Catalysis of Organic Reactions. XII. Basic Hydrolysis of Some Alkyl and Aryl N-(4-Nitrophenyl)carbamates". . p. 47 - 54. Retrieved 2007/10/02.