Rhodium tribromide

Base Information

• Chemical Name: Rhodium tribromide
• CAS No.: 15608-29-4
• Molecular Formula: Br3Rh
• Molecular Weight: 342.618
• European Community (EC) Number: 239-687-9
• Wikidata: Q4096893
• Mol file: 15608-29-4.mol

Synonyms:Rhodium tribromide;Tribromorhodium;rhodium(3+) tribromide;CS-0085053;A890794;Q4096893

Chemical Property of Rhodium tribromide

Chemical Property:

• PSA: 18.46000
• Density: 5.59 g/mL.
• LogP: 2.40820
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 341.65846
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%min ^*data from raw suppliers

Rhodium(III) bromide dihydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Br[Rh](Br)Br

Technology Process of Rhodium tribromide

There total 4 articles about Rhodium tribromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetra[μ-acetato-bis(methanol)]dirhodium + hydrogen bromide (10035-10-6,12258-64-9) → rhodium(III) bromide (15608-29-4) + rhodium (378784-00-0,7440-16-6)

Guidance literature:

DOI:10.1021/ic50163a042 DOI:10.1016/S0020-1693(00)89485-2

Reference yield:

rhodium (378784-00-0,7440-16-6) → rhodium(III) bromide (15608-29-4)

Guidance literature:

With bromine; passing over of Br2-vapors in a CO2-stream at 200-300 °C;; contaminated with Rh and Br2 because of equilibrium (temperature depending);;

Reference yield:

hydrogen bromide (10035-10-6,12258-64-9) + rhodium(III)chloride (10049-07-7) → rhodium(III) bromide (15608-29-4)

Guidance literature:

In hydrogen bromide; HBr (liquid); slow evapn. of RhCl3 dissolved in excess of HBr several times;;

DOI:10.1016/S0020-1693(00)85181-6

upstream raw materials:

bromine

rhodium

hydrogen bromide

rhodium(III)chloride

Downstream raw materials:

Pyridine hydrobromide

[Rh(7-chloro-1,3-dihydro-5-phenyl-3-hydroxy-2H-1,4-benzodiazepin-2-one)3Br₃]

[RhBr₃((C₆H₅)2SbCH₂Sb(C₆H₅)2)2]

[RhBr₃((C₆H₅)2SbCH₂Sb(C₆H₅)2)2]

Refernces