dicyano diisopropylamino phosphane

Base Information

• Chemical Name: dicyano diisopropylamino phosphane
• CAS No.: 122947-30-2
• Molecular Formula: C₈H₁₄N₃P
• Molecular Weight: 183.193
• Mol file: 122947-30-2.mol

Synonyms:dicyano diisopropylamino phosphane

Chemical Property of dicyano diisopropylamino phosphane

Chemical Property:

Purity/Quality:

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Technology Process of dicyano diisopropylamino phosphane

There total 2 articles about dicyano diisopropylamino phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

tert-butylisonitrile (119072-55-8,7188-38-7) + bis(diisopropylamino)phosphenium trifluoromethanesulfonate → dicyano diisopropylamino phosphane (122947-30-2) + diisopropylammonium trifluoromethanesulfonate (77534-66-8) + isobutene (115-11-7,15220-85-6)

Guidance literature:

In dichloromethane; at 20 ℃; Product distribution; Mechanism;

DOI:10.1021/jo00284a027

Reference yield:

tert-butylisonitrile (119072-55-8,7188-38-7) + bis(diisopropylamino)phosphenium trifluoromethanesulfonate → dicyano diisopropylamino phosphane (122947-30-2) + bis(diisopropylamino)phosphanylnitrile (97135-49-4) + (diisopropylamino)cyanophosphenium trifluoromethanesulfonate (114684-85-4) + diisopropylammonium trifluoromethanesulfonate (77534-66-8) + isobutene (115-11-7,15220-85-6)

Guidance literature:

In dichloromethane; at -50 ℃; Product distribution; Mechanism;

DOI:10.1021/jo00284a027

Reference yield:

dicyano diisopropylamino phosphane (122947-30-2) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → C20H25N3P2

Guidance literature:

dicyano diisopropylamino phosphane; With Schwartz's reagent; In dichloromethane; at 0 ℃; for 1h;

chloro-diphenylphosphine; In dichloromethane; at -78 - 0 ℃; Further stages.;

DOI:10.1002/ejoc.200390045

upstream raw materials:

tert-butylisonitrile

Refernces