Rh(tmp)i-Bu

Base Information

• Chemical Name: Rh(tmp)i-Bu
• CAS No.: 1201111-94-5
• Molecular Formula: C₆₀H₆₁N₄Rh
• Molecular Weight: 941.077
• Mol file: 1201111-94-5.mol

Synonyms:Rh(tmp)i-Bu

Chemical Property of Rh(tmp)i-Bu

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(tmp)i-Bu

There total 2 articles about Rh(tmp)i-Bu which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) + isopentyl ether (544-01-4) → isopentyl formate (110-45-2) + Rh(tmp)i-Bu (1201111-94-5)

Guidance literature:

With water; tetraphenylphosphonium bromide; triphenylphosphine; potassium hydroxide; at 25 ℃; for 2h; regioselective reaction; Inert atmosphere; Darkness;

DOI:10.1021/om200280w

Reference yield: 1.0%

isopentyl ether (544-01-4) + (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide (85990-32-5) → Rh(tmp)i-Bu (1201111-94-5)

Guidance literature:

With KOH; In further solvent(s); reaction of rhodium compd. with diisopentyl ether in presence of 10 equiv. of KOH at 100°C for 1 d under N2;

DOI:10.1021/om900270v

upstream raw materials:

isopentyl ether

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

Refernces

• 1、 Lai, Tsz Ho,Chan, Kin Shing. "Base-promoted, selective aliphatic carbon-carbon bond cleavage of ethers by rhodium(III) porphyrin complexes". . p. 6845 - 6846. Retrieved 2010/04/04.