8-Phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

Base Information

• Chemical Name: 8-Phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole
• CAS No.: 57680-64-5
• Molecular Formula: C₁₀H₁₄NO₂P
• Molecular Weight: 211.2
• Mol file: 57680-64-5.mol

Synonyms:8-Phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

Chemical Property of 8-Phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 8-Phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

There total 1 articles about 8-Phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 8-Phenyl-tetrahydro-8λ5-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole (57680-64-5)

Guidance literature:

PhP(NMe2)2, /BRN= 605315/;

Reference yield: 100.0%

Dimethyldisulphide (624-92-0) + 8-Phenyl-tetrahydro-8λ5-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole (57680-64-5) → 6a-Methylsulfanyl-6a-phenyl-tetrahydro-1,6-dioxa-3a-aza-6aλ5-phospha-pentalene

Guidance literature:

In benzene; for 2h; Irradiation; var. time;

DOI:10.1021/ja00238a036

Reference yield: 96.0%

di(rhodium)tetracarbonyl dichloride + 8-Phenyl-tetrahydro-8λ5-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole (57680-64-5) + phenol (108-95-2,27073-41-2) → {Rh(CO)Cl(P(OC6H5)(OC2H4)2NH)} (153006-18-9)

Guidance literature:

In dichloromethane; (under Ar) PhOH in CH2Cl2 is added dropwise with stirring to a soln. of BAP in CH2Cl2, the soln. is stirred for 1 h and then is added (Rh(CO)2Cl)2 in CH2Cl2; ppt. is separated, washed with ether and pentane and dried in air in vac. (1mm Hg), elem. anal.;

DOI:10.1016/0022-328X(93)83296-8

Downstream raw materials:

(8-TB-5-22)-8-butylsulfanyl-8-phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

2-Phenyl-[1,3,6,2]dioxazaphosphocane 2-sulfide

6a-Phenyl-6a-phenylsulfanyl-tetrahydro-1,6-dioxa-3a-aza-6aλ⁵-phospha-pentalene

(8-TB-5-11)-8-ethoxy-8-phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole