2 3 9 10 16 17 23 24-OCTAKIS(OCTYLOXY)-&

Base Information

• Chemical Name: 2 3 9 10 16 17 23 24-OCTAKIS(OCTYLOXY)-&
• CAS No.: 119457-81-7
• Molecular Formula: C96H146 N8 O8
• Molecular Weight: 1540.26
• Mol file: 119457-81-7.mol

Synonyms:2 3 9 10 16 17 23 24-OCTAKIS(OCTYLOXY)-&;2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-ph

Chemical Property of 2 3 9 10 16 17 23 24-OCTAKIS(OCTYLOXY)-&

Chemical Property:

• Melting Point: >300 °C(lit.)
• PSA: 179.58000
• Density: 1.059±0.06 g/cm3(Predicted)
• LogP: 23.80720

Purity/Quality:

99%, ^*data from raw suppliers

2,3,9,10,16,17,23,24-Octakis(octyloxy)-29H,31H-phthalocyanine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2 3 9 10 16 17 23 24-OCTAKIS(OCTYLOXY)-&

There total 1 articles about 2 3 9 10 16 17 23 24-OCTAKIS(OCTYLOXY)-& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.6%

1,3-dihydro-1,3-diimino-5,6-bis(octyloxy)isoindole (118156-18-6) → C96H144Cl2N8O8Si + 1,2-dicyano-4,5-bis(n-octyloxy)benzene (118132-11-9) + 5,6-Bis-octyloxy-isoindole-1,3-dione + 2,3,9,10,16,17,23,24-octakis(octyloxy)-19H,31H-phthalocyanine (119457-81-7)

Guidance literature:

With quinoline; tetrachlorosilane; at 190 ℃; for 1h;

Reference yield: 32.0%

2,3,9,10,16,17,23,24-octakis(octyloxy)phthalocyanine (119457-81-7) + samarium(III) acetylacetonate hydrate + 2,3-dicyanonaphthalene (22856-30-0) → bis(2,3,9,10,16,17,24,25-oktakis(octyloxy)phthalocyaninato)samarium(III) + Sm(2,3-naphthalocyaninato)[2,3,9,10,16,17,24,25-octakis(octyloxy)phthalocyaninato]

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In further solvent(s); mixt. H2Pc, Sm(acac)3*nH2O, and dicyanonaphthalene in n-octanol in the presenceof DBU was heated at 150°C for 2 h and then heated to reflux for 7 h under N2 stream; soln. was cooled to room temp., volatiles were removed in vacuo, residuewas chromed. with CHCl3, recrystn. from CHCl3-MeOH; elem. anal.;

DOI:10.1021/ic048472s

Reference yield: 20.0%

5,15-bis[4-(phenylethynyl)phenyl]porphyrin + 2,3,9,10,16,17,23,24-octakis(octyloxy)-19H,31H-phthalocyanine (119457-81-7) → C144H172CeN12O8

Guidance literature:

2,3,9,10,16,17,23,24-octakis(octyloxy)-19H,31H-phthalocyanine; With cerium(III) acetylacetonate hydrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; hexan-1-ol; at 155 ℃; for 4.5h; Inert atmosphere;

5,15-bis[4-(phenylethynyl)phenyl]porphyrin; In toluene; hexan-1-ol; for 19h; Inert atmosphere; Reflux;

DOI:10.1246/cl.2011.717

upstream raw materials:

1,3-dihydro-1,3-diimino-5,6-bis(octyloxy)isoindole

Refernces