Technology Process of Mo2(μ-SPh)2Cl4(3,6-dithiaoctane)2
There total 3 articles about Mo2(μ-SPh)2Cl4(3,6-dithiaoctane)2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
methanol;
Mo2-complex and PhSSPh were stirred and refluxed together in MeOH underinert atmosphere; the vol. of the soln. was reduced by evapn. under a stream of N2, ppt. was filtered off, washed with hexane, dried in vacuo; identified by IR spectrum;
DOI:10.1021/ja00311a036
- Guidance literature:
-
In
methanol;
a mixt. of K4Mo2Cl8, PhSSPh, and EtSCH2CH2SEt in MeOH was refluxed for 2 d under inert atmosphere; one more unidentified product was isolated from the reaction; cooled at 5°C for 1 d, filtered, filtrate was pumped to dryness under vac., residue extd. with CH2Cl2, ext. cooled at -10°C for several days, filtered, combined ppts. were washed with water, hexane, dried in vacuo;
DOI:10.1021/ja00311a036
- Guidance literature:
-
In
methanol;
Mo-compd., 3,6-dithiaoctane and PhS2Ph (molar ratio 1:2:1) were refluxed in MeOH for 3-5 h;
DOI:10.1021/ja00323a062
