2-(BICYCLOHEPTYL)DIMETHYLCHLOROSILANE

Base Information

• Chemical Name: 2-(BICYCLOHEPTYL)DIMETHYLCHLOROSILANE
• CAS No.: 117046-42-1
• Molecular Formula: C₉H₁₇ClSi
• Molecular Weight: 188.772
• Mol file: 117046-42-1.mol

Synonyms:Silane,bicyclo[2.2.1]hept-2-ylchlorodimethyl- (9CI);Norbornyldimethylchlorosilane;

Chemical Property of 2-(BICYCLOHEPTYL)DIMETHYLCHLOROSILANE

Chemical Property:

• Vapor Pressure: 0.288mmHg at 25°C
• Melting Point: <0 °C
• Refractive Index: 1.474
• Boiling Point: 209.8 °C at 760 mmHg
• Flash Point: 73 °C
• PSA: 0.00000
• Density: 0.99 g/cm³
• LogP: 3.62050

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bicyclo[2.2.1]heptan-2-ylchlorodimethylsilane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R20/21/22-34-36/37/38:
• Hazard Codes: R20/21/22-34-36/37/38:
• Statements: 20/21/22-34-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(BICYCLOHEPTYL)DIMETHYLCHLOROSILANE

There total 3 articles about 2-(BICYCLOHEPTYL)DIMETHYLCHLOROSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

norborn-2-ene (498-66-8) + dimethylmonochlorosilane (1066-35-9) → 2-norbornyldimethylchlorosilane (117046-42-1)

Guidance literature:

With C₂₄H₄₈O₇PtSi₂; 1,3,5-trimethyl-benzene; In toluene; at 20 ℃; for 0.333333h; Reagent/catalyst; Schlenk technique; Inert atmosphere;

Reference yield: 81.0%

norborn-2-ene (498-66-8) + dimethylmonochlorosilane (1066-35-9) → exo-2-(dimethylchlorosilyl)bicyclo<2.2.1>heptane (65118-95-8,117046-42-1)

Guidance literature:

platinum; In toluene; at 80 ℃; for 0.25h;

DOI:10.1021/jo00386a003

Reference yield:

dimethylmonochlorosilane (1066-35-9) + norbornene (498-66-8) → 2-norbornyldimethylchlorosilane (117046-42-1)

Guidance literature:

norbornene; With [Pt]/maleic anhydride modified PEG⁽⁶⁰⁰⁾; for 0.0833333h;

dimethylmonochlorosilane; at 60 ℃; for 3h; regioselective reaction;

DOI:10.1002/aoc.1776

upstream raw materials:

norborn-2-ene

dimethylmonochlorosilane

norbornene

Refernces

• 1、 -. "Metal complex and supported metal complex having disiloxane as ligand, method for production therefor, and supported metal catalyst prepared by using the same". Page/Page column 15. . Retrieved 2019/03/17.
• 2、 Bai, Ying,Peng, Jiajian,Li, Jiayun,Lai, Guoqiao. "Use of carboxylated polyethylene glycol as promoter for platinum-catalyzed hydrosilylation of alkenes". experimental part. p. 400 - 405. Retrieved 2012/04/17.