Technology Process of meso-triphenylporphyrin
There total 10 articles about meso-triphenylporphyrin which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 70 percent / conc. HBr, conc. H2SO4 / 10 h / Heating
2: 98 percent / thionyl chloride / 1.) room temperature, 1 h, 2.) reflux
3: pyridine / CH2Cl2 / 12 h
4: 93 percent / NaOH / dimethylformamide / 12 h / Ambient temperature; pH 8
5: 1.) mercuric acetate, 2.) hydrogen sulfide gas / 1.) ethanol, room temperature, 6 h, 2.) 3 h
With
pyridine; sodium hydroxide; thionyl chloride; sulfuric acid; hydrogen sulfide; mercury(II) diacetate; hydrogen bromide;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00369a041
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 98 percent / thionyl chloride / 1.) room temperature, 1 h, 2.) reflux
2: pyridine / CH2Cl2 / 12 h
3: 93 percent / NaOH / dimethylformamide / 12 h / Ambient temperature; pH 8
4: 1.) mercuric acetate, 2.) hydrogen sulfide gas / 1.) ethanol, room temperature, 6 h, 2.) 3 h
With
pyridine; sodium hydroxide; thionyl chloride; hydrogen sulfide; mercury(II) diacetate;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00369a041
- Guidance literature:
-
With
ammonia;
In
methanol; chloroform;
for 12h;
Ambient temperature;
DOI:10.1021/ja00369a041