C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol

Base Information

• Chemical Name: C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol
• CAS No.: 664340-98-1
• Molecular Formula: C₄₃H₈₀O₄
• Molecular Weight: 667.058
• Mol file: 664340-98-1.mol

Synonyms:C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol

Chemical Property of C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol

There total 2 articles about C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

3,4,5-tris(1,1-dideuteriododecyloxy)benzoic acid ethyl ester (664340-96-9) → C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol (664340-98-1)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1021/ja0366179

Reference yield:

1-bromo-1,1-dideuteriododecane (2159-25-3) → C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol (664340-98-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / K₂CO₃ / acetone / Heating

2: 99 percent / LiAH₄ / diethyl ether

With lithium aluminium tetrahydride; potassium carbonate; In diethyl ether; acetone;

DOI:10.1021/ja0366179

Reference yield: 94.0%

C-3,4,5-tris(1,1-dideuteriododecyloxy)phenylmethanol (664340-98-1) → C-3,4,5-tris(1,1-dideuteriododecyloxy)benzaldehyde (664340-91-4)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; at 20 ℃;

DOI:10.1021/ja0366179

upstream raw materials:

3,4,5-tris(1,1-dideuteriododecyloxy)benzoic acid ethyl ester

1-bromo-1,1-dideuteriododecane

Downstream raw materials:

C-3,4,5-tris(1,1-dideuteriododecyloxy)benzaldehyde

Refernces