(1S)-(+)-4-OXOMYRTENYL PIVALATE, 97

Base Information Edit

Chemical Name:(1S)-(+)-4-OXOMYRTENYL PIVALATE, 97
CAS No.:113473-32-8
Molecular Formula:C15H22 O3
Molecular Weight:250.338
Hs Code.:
Mol file:113473-32-8.mol

Synonyms:Propanoicacid, 2,2-dimethyl-, (6,6-dimethyl-4-oxobicyclo[3.1.1]hept-2-en-2-yl)methylester, (1S)-; 4-Oxomyrtenol pivalate; 4-Oxomyrtenyl pivalate

Suppliers and Price of (1S)-(+)-4-OXOMYRTENYL PIVALATE, 97

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(1S)-(+)-4-OXOMYRTENYL PIVALATE 95.00%
5MG
$ 505.10

Total 1 raw suppliers

Chemical Property of (1S)-(+)-4-OXOMYRTENYL PIVALATE, 97 Edit

Chemical Property:

Vapor Pressure:0.000128mmHg at 25°C
Melting Point:40-44 °C(lit.)
Refractive Index:1.49
Boiling Point:334.5°Cat760mmHg
Flash Point:143.7°C
PSA：43.37000
Density:1.049g/cm³
LogP:2.74710

Purity/Quality:

99%min ^*data from raw suppliers

(1S)-(+)-4-OXOMYRTENYL PIVALATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1S)-(+)-4-OXOMYRTENYL PIVALATE, 97

There total 13 articles about (1S)-(+)-4-OXOMYRTENYL PIVALATE, 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 113473-31-7
[(1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl 2,2-dimethylpropanoate

: 113473-32-8
[(1S,5R)-6,6-dimethyl-4-oxobicyclo[3.1.1]hept-2-en-2-yl]methyl 2,2-dimethylpropanoate

Guidance literature:: With 3,5-dimethyl-1H-pyrazole; chromium(VI) oxide; In dichloromethane; at -20 ℃; for 4h; Inert atmosphere;
DOI:10.1016/j.ejmech.2021.113878

Reference yield:

: 3282-30-2
pivaloyl chloride

: 95925-03-4
10-hydroxyverbenone

: 113473-32-8
[(1S,5R)-6,6-dimethyl-4-oxobicyclo[3.1.1]hept-2-en-2-yl]methyl 2,2-dimethylpropanoate

Guidance literature:: With pyridine; In dichloromethane; Inert atmosphere; Cooling with ice;

Reference yield:

: 7785-70-8,25766-18-1
(+)-α-pinene

: 113473-32-8
[(1S,5R)-6,6-dimethyl-4-oxobicyclo[3.1.1]hept-2-en-2-yl]methyl 2,2-dimethylpropanoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: selenium(IV) oxide / ethanol / 3 h / 75 °C / Inert atmosphere

1.2: 1 h / Inert atmosphere

2.1: pyridine / dichloromethane / 4 h / 0 °C / Inert atmosphere

3.1: chromium(VI) oxide; 3,5-dimethyl-1H-pyrazole / dichloromethane / 4 h / -20 °C / Inert atmosphere

With pyridine; 3,5-dimethyl-1H-pyrazole; chromium(VI) oxide; selenium(IV) oxide; In ethanol; dichloromethane;
DOI:10.1039/C6OB02796B