(17s,18s,19s,20s)-17,18,19,20-tetraundecyl-3⁴,3⁵,7⁴,7⁵,11⁴,11⁵,15⁴,15⁵-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.1^1,5.1^5,9.1^9,13]icosaphane

Base Information

• Chemical Name: (17s,18s,19s,20s)-17,18,19,20-tetraundecyl-3⁴,3⁵,7⁴,7⁵,11⁴,11⁵,15⁴,15⁵-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.1^1,5.1^5,9.1^9,13]icosaphane
• CAS No.: 196860-34-1
• Molecular Formula: C₉₆H₁₁₂N₈O₂₄
• Molecular Weight: 1761.98
• Mol file: 196860-34-1.mol

Synonyms:(17s,18s,19s,20s)-17,18,19,20-tetraundecyl-3⁴,3⁵,7⁴,7⁵,11⁴,11⁵,15⁴,15⁵-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.1^1,5.1^5,9.1^9,13]icosaphane

Chemical Property of (17s,18s,19s,20s)-17,18,19,20-tetraundecyl-3⁴,3⁵,7⁴,7⁵,11⁴,11⁵,15⁴,15⁵-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.1^1,5.1^5,9.1^9,13]icosaphane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (17s,18s,19s,20s)-17,18,19,20-tetraundecyl-3⁴,3⁵,7⁴,7⁵,11⁴,11⁵,15⁴,15⁵-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.1^1,5.1^5,9.1^9,13]icosaphane

There total 2 articles about (17s,18s,19s,20s)-17,18,19,20-tetraundecyl-3⁴,3⁵,7⁴,7⁵,11⁴,11⁵,15⁴,15⁵-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.1^1,5.1^5,9.1^9,13]icosaphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

C-undecylcalix[4]resorcinarene (847018-76-2,112247-07-1) + 1,2-dinitro-4,5-difluorobenzene (85686-97-1) → (17s,18s,19s,20s)-17,18,19,20-tetraundecyl-34,35,74,75,114,115,154,155-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.11,5.15,9.19,13]icosaphane (196860-34-1)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; at 70 ℃; for 16h;

DOI:10.1021/jo990209z

Reference yield: 57.0%

C-undecylcalix[4]resorcinarene (847018-76-2,112247-07-1) + 1,2-dinitro-4,5-difluorobenzene (85686-97-1) → (17s,18s,19s,20s)-17,18,19,20-tetraundecyl-34,35,74,75,114,115,154,155-octanitro-2,4,6,8,10,12,14,16-octaoxa-3,7,11,15(1,2),1,5,9,13(1,2,4,5)-octabenzenapentacyclo[11.3.1.11,5.15,9.19,13]icosaphane (196860-34-1) + C90H112N6O20

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; at 70 ℃; for 16h;

DOI:10.1021/ja993922e

upstream raw materials:

C-undecylcalix[4]resorcinarene

1,2-dinitro-4,5-difluorobenzene

Refernces

• 1、 Tucci, Fabio C.,Rudkevich, Dmitry M.,Rebek Jr., Julius. "Deeper cavitands". . p. 4555 - 4559. Retrieved 1999.
• 2、 Menozzi, Edoardo,Onagi, Hideki,Rheingold, Arnold L.,Rebek Jr., Julius. "Extended cavitands of nanoscale dimensions". . p. 3633 - 3636. Retrieved 2005.
• 3、 Dumele, Oliver,Trapp, Nils,Diederich, Fran?ois. "Halogen Bonding Molecular Capsules". supporting information. p. 12339 - 12344. Retrieved 2015/10/12.