Ru(CO)3(PPh₃)3

Base Information

• Chemical Name: Ru(CO)3(PPh₃)3
• CAS No.: 151757-44-7
• Molecular Formula: C₅₇H₄₅O₃P₃Ru
• Molecular Weight: 971.974
• Mol file: 151757-44-7.mol

Synonyms:Ru(CO)3(PPh₃)3

Chemical Property of Ru(CO)3(PPh₃)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(CO)3(PPh₃)3

There total 2 articles about Ru(CO)3(PPh₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aquahydridohydroxobis(triphenylphosphine)ruthenium(II) (63827-91-8) → Ru(CO)3(PPh3)3 (151757-44-7)

Guidance literature:

With carbon monoxide; In not given; Ar-atmosphere;

DOI:10.1039/DT9770001546

Reference yield:

hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II) (65465-08-9) → Ru(CO)3(PPh3)3 (151757-44-7)

Guidance literature:

With carbon monoxide; In not given;

DOI:10.1039/DT9770001546

Reference yield:

trithiazyl trichloride (105454-00-0,105453-99-4,5964-00-1) + Ru(CO)3(PPh3)3 (151757-44-7) → dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3) + tetrasulfur tetranitride (28950-34-7)

Guidance literature:

In tetrahydrofuran; dropwise addn. of (NSCl)3 in THF to a stirred soln. of Ru-complex in THF at 10°C, stirring for 1 h more; concn. to a smaller volume, addn. of hexane in excess, pptn., centrifugation, washing several times with hexane, drying filtrate in vacuo yields S4N4, elem. anal.;

upstream raw materials:

aquahydridohydroxobis(triphenylphosphine)ruthenium(II)

hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II)

Downstream raw materials:

dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

tetrasulfur tetranitride