tetra-n-butylammonium dibenzyl phosphate

Base Information

• Chemical Name: tetra-n-butylammonium dibenzyl phosphate
• CAS No.: 77772-62-4
• Molecular Formula: C₁₄H₁₄O₄P*C₁₆H₃₆N
• Molecular Weight: 519.705
• Mol file: 77772-62-4.mol

Synonyms:tetra-n-butylammonium dibenzyl phosphate

Chemical Property of tetra-n-butylammonium dibenzyl phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of tetra-n-butylammonium dibenzyl phosphate

There total 3 articles about tetra-n-butylammonium dibenzyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

phosphoric acid dibenzyl ester (1623-08-1) + tetra(n-butyl)ammonium hydroxide (2052-49-5) → tetra-n-butylammonium dibenzyl phosphate (77772-62-4)

Guidance literature:

In water; at 60 ℃; for 2h;

DOI:10.1021/jacs.0c03207

Reference yield: 95.0%

silver dibenzylphosphate (50651-75-7) + tetrabutylammomium bromide (1643-19-2) → tetra-n-butylammonium dibenzyl phosphate (77772-62-4)

Guidance literature:

In methanol; dichloromethane; for 2h; Ambient temperature;

DOI:10.1021/jo9823745

Reference yield:

phosphoric acid dibenzyl ester (1623-08-1) → tetra-n-butylammonium dibenzyl phosphate (77772-62-4)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In water;

upstream raw materials:

phosphoric acid dibenzyl ester

tetra(n-butyl)ammonium hydroxide

silver dibenzylphosphate

tetrabutylammomium bromide

Downstream raw materials:

dibenzylphosphoryl 2,3,4-tri-O-acetyl-L-fucoside

N⁴-benzoylcytidin-5'-yl dibenzyl phosphate

methyl-2,3-didehydro-4,7,8,9-tetra-O-acetyl-N-acetylneuraminate

methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-2-O-dibenzyloxyphosphoryl-3,5-dideoxy-β-D-glycero-D-galacto-non-2-ulopyranosonate

Refernces

• 1、 Li, Xiangyu,Hall, Dennis G.. "Stereodivergent Asymmetric Synthesis of α,β-Disubstituted β-Aminoalkylboronic Acid Derivatives via Group-Selective Protodeboronation Enabling Access to the Elusive Anti Isomer". supporting information. p. 9063 - 9069. Retrieved 2020/12/23.
• 2、 -. "Prodrugs of paclitaxel derivatives". . . Retrieved 2008/06/13.