Technology Process of 5,6,12,13-tetrachloro-2,9-bis(3-(4-(4-((4,6-diamino-1,3,5-triazin-2-yl)methyl)phenyl)-1H-1,2,3-triazol-1-yl)propyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
There total 3 articles about 5,6,12,13-tetrachloro-2,9-bis(3-(4-(4-((4,6-diamino-1,3,5-triazin-2-yl)methyl)phenyl)-1H-1,2,3-triazol-1-yl)propyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
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1353346-40-3
5,6,12,13-tetrachloro-2,9-bis(3-(4-(4-((4,6-diamino-1,3,5-triazin-2-yl)methyl)phenyl)-1H-1,2,3-triazol-1-yl)propyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Guidance literature:
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With
copper(l) iodide; N-ethyl-N,N-diisopropylamine; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine;
In
water; isopropyl alcohol; toluene;
at 90 ℃;
for 7h;
cavity resonator;
DOI:10.1016/j.tet.2011.10.096
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1353346-40-3
5,6,12,13-tetrachloro-2,9-bis(3-(4-(4-((4,6-diamino-1,3,5-triazin-2-yl)methyl)phenyl)-1H-1,2,3-triazol-1-yl)propyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Guidance literature:
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Multi-step reaction with 3 steps
1: chlorosulfonic acid; iodine / 5 h / 70 °C
2: toluene / 4 h / Inert atmosphere; Reflux
3: copper(l) iodide; N-ethyl-N,N-diisopropylamine; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine / water; isopropyl alcohol; toluene / 7 h / 90 °C / cavity resonator
With
chlorosulfonic acid; copper(l) iodide; iodine; N-ethyl-N,N-diisopropylamine; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine;
In
water; isopropyl alcohol; toluene;
DOI:10.1016/j.tet.2011.10.096
-
-
1353346-40-3
5,6,12,13-tetrachloro-2,9-bis(3-(4-(4-((4,6-diamino-1,3,5-triazin-2-yl)methyl)phenyl)-1H-1,2,3-triazol-1-yl)propyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Guidance literature:
-
Multi-step reaction with 2 steps
1: toluene / 4 h / Inert atmosphere; Reflux
2: copper(l) iodide; N-ethyl-N,N-diisopropylamine; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine / water; isopropyl alcohol; toluene / 7 h / 90 °C / cavity resonator
With
copper(l) iodide; N-ethyl-N,N-diisopropylamine; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine;
In
water; isopropyl alcohol; toluene;
DOI:10.1016/j.tet.2011.10.096