D-FRUCTOSE-1-13C

Base Information

• Chemical Name: D-FRUCTOSE-1-13C
• CAS No.: 108311-21-3
• Molecular Formula: C6H12 O6
• Molecular Weight: 181.147
• Mol file: 108311-21-3.mol

Synonyms:D-[1-13C]FRUCTOSE;D-FRUCTOSE-1-13C;D-FRUCTOSE (1-13C, 99%);fructose-1-C13

Chemical Property of D-FRUCTOSE-1-13C

Chemical Property:

• Melting Point: 119-122 °C (dec.)(lit.)
• Refractive Index: 1.645
• PSA: 110.38000
• Density: 1.758g/cm³
• LogP: -3.21980

Purity/Quality:

95% ^*data from raw suppliers

D-Fructose-1-13C ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Isotope labelled D-Fructose (F792500), a monosaccharide that naturally occurs in large number of fruits and plants.

Technology Process of D-FRUCTOSE-1-13C

There total 6 articles about D-FRUCTOSE-1-13C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

α- and β-D-<1-13C>mannose (40010-55-7,40010-56-8,56746-22-6,60821-16-1,60821-17-2,60821-20-7,60821-21-8) → [1-13C]D-glucose (40762-22-9,478519-02-7) + <1-13C>-D-fructose (108311-21-3)

Guidance literature:

at 25 ℃; mildly basic condition; equilibrium;

DOI:10.1016/S0008-6215(00)90019-3

Reference yield:

13C-C1-glucopyranose (40010-55-7,40010-56-8,56746-22-6,60821-16-1,60821-17-2,60821-20-7,60821-21-8) → <2-13C>-D-fructose (117013-19-1) + <1-13C>-D-fructose (108311-21-3) + [2-13C]-D-mannopyranoside (105931-74-6)

Guidance literature:

With sodium hydroxide; calcium chloride; In methanol; at 65 ℃; for 0.0833333h; Product distribution; also in water with Ca(OH)2;

Reference yield:

[1-13C]D-glucose (40762-22-9,478519-02-7) → C5(13)CH12O6 (478506-38-6) + <1-13C>-D-fructose (108311-21-3)

Guidance literature:

With silica zeolite beta containing Lewis acidic framework Ti⁴⁺ ; In water; at 99.84 ℃;

upstream raw materials:

¹³C-C₁-glucopyranose

α- and β-D-<1-13C>mannose

[1-13C]D-glucose

Downstream raw materials:

furan

<α-¹³C>-Furan

Refernces

• 1、 Yanagihara, Ryoji,Osanai, Shuichi,Yoshikawa, Sadao. "C-1,C-2 Stereospecific Rearrangements of Aldohexoses by Calcium Ion in Basic Solution". . p. 2273 - 2276. Retrieved 2007/10/02.