1H,1H,2H,3H,3H-PERFLUORONONANE-1,2-DIOL

Base Information

• Chemical Name: 1H,1H,2H,3H,3H-PERFLUORONONANE-1,2-DIOL
• CAS No.: 107650-06-6
• Molecular Formula: C9H7 F13 O2
• Molecular Weight: 394.133
• Hs Code.: 2905590090
• Mol file: 107650-06-6.mol

Synonyms:1H,1H,2H,2H-PERFLUORONONANE-1,2-DIOL;1H,1H,2H,3H,3H-PERFLUORONONANE-1,2-DIOL;Perfluorononanediol;1H,1H,2H,3H,3H-Perfluorononane-1,2-diol 97%;1H,1H,2H,3H,3H-Perfluorononane-1,2-diol97%

Chemical Property of 1H,1H,2H,3H,3H-PERFLUORONONANE-1,2-DIOL

Chemical Property:

• Vapor Pressure: 0.0432mmHg at 25°C
• Melting Point: 63-64°C
• Refractive Index: 1.322
• Boiling Point: 120-130°C
• PKA: 13.52±0.20(Predicted)
• Flash Point: 81.2°C
• PSA: 40.46000
• Density: 1.617g/cm³
• LogP: 3.46850

Purity/Quality:

98%min ^*data from raw suppliers

1H,1H,2H,3H,3H-Perfluorononane-1,2-diol ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1H,1H,2H,3H,3H-PERFLUORONONANE-1,2-DIOL

There total 3 articles about 1H,1H,2H,3H,3H-PERFLUORONONANE-1,2-DIOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptan-1-yl)-2,2-dimethyl-1,3-dioxolane (196513-81-2) → 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononane-1,2-diol (107650-06-6)

Guidance literature:

With hydrogenchloride; methanol; for 2h; Heating;

DOI:10.1016/S0022-1139(97)00032-8

Reference yield: 90.0%

3-(perfluorohexyl)prop-1-ene (80793-18-6) → 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononane-1,2-diol (107650-06-6)

Guidance literature:

With osmium(VIII) oxide; bis-(2-chloro-ethyl)-methyl-amine oxide; In acetone; tert-butyl alcohol; at 20 ℃; for 24h;

DOI:10.1016/j.jfluchem.2004.04.011

Reference yield:

2-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl)oxirane (38565-52-5) → 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononane-1,2-diol (107650-06-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / BF₃*Et₂O / 0.5 h / Heating

2: 96 percent / aq. HCl, MeOH / 2 h / Heating

With hydrogenchloride; methanol; boron trifluoride diethyl etherate;

DOI:10.1016/S0022-1139(97)00032-8

upstream raw materials:

4-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptan-1-yl)-2,2-dimethyl-1,3-dioxolane

3-(perfluorohexyl)prop-1-ene

2-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl)oxirane

Downstream raw materials:

diethyl 2-(1H,1H-perfluoroheptyl)-2,3-dihydrothieno[3,4-b]-[1,4]-dioxine-5,7-dicarboxylate

Refernces

• 1、 Cirkva, Vladimir,Ameduri, Bruno,Boutevin, Bernard,Paleta, Oldrich. "Chemistry of [(perfluoroalkyl)methyl] oxiranes. Regioselectivity of ring opening with O-nucleophiles and the preparation of amphiphilic monomers". . p. 53 - 61. Retrieved 2007/10/03.