5,9,14,18,23,27,32,36-OCTABUTOXY- 2,3-NAPHTHALOCYANINE

Base Information

• Chemical Name: 5,9,14,18,23,27,32,36-OCTABUTOXY- 2,3-NAPHTHALOCYANINE
• CAS No.: 105528-25-4
• Molecular Formula: C80H90N8O8
• Molecular Weight: 1291.64
• Mol file: 105528-25-4.mol

Synonyms:5,9,14,18,23,27,32,36-Octabutoxynaphthalocyanine;

Chemical Property of 5,9,14,18,23,27,32,36-OCTABUTOXY- 2,3-NAPHTHALOCYANINE

Chemical Property:

• Melting Point: 303 °C
• PSA: 179.58000
• Density: 1.215 g/cm³
• LogP: 15.93680

Purity/Quality:

98%,99%, ^*data from raw suppliers

5,9,14,18,23,27,32,36-Octabutoxy-2,3-naphthalocyanine Dye content 95 % ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,9,14,18,23,27,32,36-OCTABUTOXY- 2,3-NAPHTHALOCYANINE

There total 5 articles about 5,9,14,18,23,27,32,36-OCTABUTOXY- 2,3-NAPHTHALOCYANINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1,4-dibutoxy-2,3-naphthalocyaninedicarbonitrile (116453-89-5) → 5,9,14,18,23,27,32,36-octa-n-butoxy-2,3-naphthalocyanine (105528-25-4)

Guidance literature:

1,4-dibutoxy-2,3-naphthalocyaninedicarbonitrile; With lithium chloride; sodium t-butanolate; In butan-1-ol; at 90 ℃; for 3h;

With hydroquinone; In butan-1-ol; at 90 ℃; for 1h;

With acetic acid; In chloroform; water; butan-1-ol; at 50 ℃; Product distribution / selectivity;

Reference yield: 48.0%

1,4-dibutoxy-2,3-naphthalocyaninedicarbonitrile (116453-89-5) → 5,9,14,18,23,27,32,36-octabutoxy-2,3-napthalocyanine (105528-25-4)

Guidance literature:

1,4-dibutoxy-2,3-naphthalocyaninedicarbonitrile; With lithium; In ethanol; for 1.5h; Reflux;

With pyridine; In dichloromethane;

Reference yield:

1,4-dibutoxy-2,3-naphthalocyaninedicarbonitrile (116453-89-5) → 1,4,5,8,9,12,13,16-octabutoxy-14-[3-(hydroxymethyl)phenoxy]phtalocyanine (116453-73-7) + 5,9,14,18,23,27,32,36-octa-n-butoxy-2,3-naphthalocyanine (105528-25-4) + C76H88N8O8 (191282-56-1) + C72H86N8O8 (191282-57-2)

Guidance literature:

With lithium; 3,6-dibutoxy-1,2-benzene dicarbonitrile; In butan-1-ol; for 1h; Further byproducts given; Heating;

DOI:10.1021/ja963702q

upstream raw materials:

1,4-dibutoxy-2,3-naphthalocyaninedicarbonitrile

1,4-dihydroxy-2,3-naphthalenedicarbonitrile

2,3-Dichloro-1,4-naphthoquinone

Downstream raw materials:

C₈₀H₈₈CuN₈O₈

Cu(5,9,14,18,23,27,32,36-octabutoxynaphthalocyanine(2-))

Ni(II) octabutoxynaphthalocyanine

Refernces

• 1、 -. "COMPOSITION, AND PHOTOELECTRIC CONVERSION ELEMENT AND IMAGING DEVICE THAT EMPLOY THE SAME". Paragraph 0134; 0136; 0137; 0138; 0139; 0140. . Retrieved 2019/01/23.
• 2、 -. "METHOD OF PROVING AUTHENTICITY, SIGNAL CONVERSION METHOD, POLYMER WELDING METHOD, METHOD OF PRODUCING LITHOGRAPHIC PRINTING PLATE, INK FOR PRINTING, TONER, AND HEAT RAY-SHIELDING MATERIAL, EACH USING NAPHTHALOCYANINE COMPOUND, AND METHOD OF PRODUCING NAPHTHALOCYANINE COMPOUND". Page/Page column 29. . Retrieved 2012/01/12.