((C₆H₅)3PAu)2S₂CNC₄H₈NCS₂

Base Information

• Chemical Name: ((C₆H₅)3PAu)2S₂CNC₄H₈NCS₂
• CAS No.: 1165801-05-7
• Molecular Formula: C₄₂H₃₈Au₂N₂P₂S₄
• Molecular Weight: 1154.92
• Mol file: 1165801-05-7.mol

Synonyms:((C₆H₅)3PAu)2S₂CNC₄H₈NCS₂

Chemical Property of ((C₆H₅)3PAu)2S₂CNC₄H₈NCS₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of ((C₆H₅)3PAu)2S₂CNC₄H₈NCS₂

There total 3 articles about ((C₆H₅)3PAu)2S₂CNC₄H₈NCS₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

carbon disulfide (75-15-0,12122-00-8) + (triphenylphosphine)gold(I) chloride (14243-64-2) + (C6H5)3PAuS2CNC4H8NH2(1+)*BF4(1-)=(C6H5)3PAuS2CNC4H8NH2BF4 (1165801-04-6) → ((C6H5)3PAu)2S2CNC4H8NCS2 (1165801-05-7)

Guidance literature:

With triethylamine; In dichloromethane; acetone; (aerobic conditions); addn. of amine and CS2 to a soln. of gold complex in acetone, addn. of a soln. of gold chloride complex in CH2Cl2, stirring for 1 h; evapn., addn. of Et2O, trituration in a sonic bath, filtration, washing with water, ethanol, hexane, recrystn. (CH2Cl2/ethanol); elem. anal.;

DOI:10.1021/ic802442d

Reference yield: 89.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + piperazine-N,N'-biscarbodithioic acid potassium (40839-73-4) → ((C6H5)3PAu)2S2CNC4H8NCS2 (1165801-05-7)

Guidance literature:

In methanol; dichloromethane; (aerobic conditions); addn. of a soln. of gold complex in CH2Cl2 to a soln. of ligand in methanol, stirring for 3.5 h in the dark; evapn., addn. of Et2O, trituration in a sonic bath, filtration, washing with water, ethanol, hexane;

DOI:10.1021/ic802442d

Reference yield:

piperazine-1-carbodithioic acid (99-00-3) + (triphenylphosphine)gold(I) chloride (14243-64-2) → ((C6H5)3PAu)2S2CNC4H8NCS2 (1165801-05-7)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane; methanol

2: triethylamine / dichloromethane; acetone

With triethylamine; In methanol; dichloromethane; acetone;

DOI:10.1021/ic802442d

upstream raw materials:

carbon disulfide

(triphenylphosphine)gold(I) chloride

(C₆H₅)3PAuS₂CNC₄H₈NH₂⁽¹⁺⁾*BF₄^(1-)=(C₆H₅)3PAuS₂CNC₄H₈NH₂BF₄

piperazine-N,N'-biscarbodithioic acid potassium

Refernces