mesityl(phenyl)iodonium triflouromethanesulfonate

Base Information

• Chemical Name: mesityl(phenyl)iodonium triflouromethanesulfonate
• CAS No.: 144930-50-7
• Molecular Formula: CF₃O₃S*C₁₅H₁₆I
• Molecular Weight: 472.267
• Mol file: 144930-50-7.mol

Synonyms:mesityl(phenyl)iodonium triflouromethanesulfonate

Chemical Property of mesityl(phenyl)iodonium triflouromethanesulfonate

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mesityl(phenyl)iodonium triflouromethanesulfonate

There total 10 articles about mesityl(phenyl)iodonium triflouromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

trifluorormethanesulfonic acid (1493-13-6) + diphenyliodonium acetate (14190-17-1) + 1,3,5-trimethyl-benzene (108-67-8) → mesityl(phenyl)iodonium triflouromethanesulfonate (144930-50-7)

Guidance literature:

In dichloromethane; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ja206047h

Reference yield: 95.0%

trifluorormethanesulfonic acid (1493-13-6) + [bis(acetoxy)iodo]benzene (3240-34-4) + 1,3,5-trimethyl-benzene (108-67-8) → mesityl(phenyl)iodonium triflouromethanesulfonate (144930-50-7)

Guidance literature:

In dichloromethane; at 0 - 20 ℃; for 2h;

DOI:10.1039/c5ob01174d

Reference yield: 90.0%

iodobenzene (591-50-4) + trifluorormethanesulfonic acid (1493-13-6) + 1,3,5-trimethyl-benzene (108-67-8) → mesityl(phenyl)iodonium triflouromethanesulfonate (144930-50-7)

Guidance literature:

iodobenzene; trifluorormethanesulfonic acid; With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 2h;

1,3,5-trimethyl-benzene; In dichloromethane;

DOI:10.1039/c6cc00556j

upstream raw materials:

trifluorormethanesulfonic acid

[bis(acetoxy)iodo]benzene

1,3,5-trimethyl-benzene

iodosylbenzene

Downstream raw materials:

3-(methoxy(phenyl)methyl)-2-methyl-4,5-diphenylfuran

(R)-3-(2-(4-bromophenyl)-2-phenylacetyl)oxazolidin-2-one

(R)-3-(2-phenylpropanoyl)oxazolidin-2-one

difluoromethylbenzene

Refernces

• 1、 Soldatova, Natalia S.,Semenov, Artem V.,Geyl, Kirill K.,Baykov, Sergey V.,Shetnev, Anton A.,Konstantinova, Anna S.,Korsakov, Mikhail M.,Yusubov, Mekhman S.,Postnikov, Pavel S.. "Copper-Catalyzed Selective N-Arylation of Oxadiazolones by Diaryliodonium Salts". supporting information. p. 3566 - 3576. Retrieved 2021/06/16.
• 2、 Bouquin, Maxime,Jaroschik, Florian,Taillefer, Marc. "Versatile and base-free copper-catalyzed α-arylations of aromatic ketones using diaryliodonium salts". supporting information. . Retrieved 2021/06/11.