(Rh{(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)}{(Z,Z)-1,5-cyclooctadiene})BF₄

Base Information

• Chemical Name: (Rh{(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)}{(Z,Z)-1,5-cyclooctadiene})BF₄
• CAS No.: 121826-79-7
• Molecular Formula: BF₄*C₄₆H₄₂OP₂Rh
• Molecular Weight: 862.497
• Mol file: 121826-79-7.mol

Synonyms:(Rh{(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)}{(Z,Z)-1,5-cyclooctadiene})BF₄

Chemical Property of (Rh{(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)}{(Z,Z)-1,5-cyclooctadiene})BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Rh{(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)}{(Z,Z)-1,5-cyclooctadiene})BF₄

There total 1 articles about (Rh{(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)}{(Z,Z)-1,5-cyclooctadiene})BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + (R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine) (121843-13-8,121772-83-6) → (Rh{(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)}{(Z,Z)-1,5-cyclooctadiene})BF4 (121826-79-7)

Guidance literature:

With AgBF₄; In tetrahydrofuran; byproducts: AgCl; Schlenk tube charged with (Rh(cod)Cl)2 and THF under Ar, AgBF4/THF added 15-20 min, stirring 20 min, AgCl ppt. filtered off (Celite) under Ar, C38H30OP2/THF added to yellow filtrate (1-2 h) gives orange ppt.; solid filtered under Ar, washed twice (THF), dried (vac.), elem. anal.;

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

(R)-5,7-dihydrodibenz{c,e}oxepin-1,11-bis(diphenylphosphine)