methoxytriphenylstannane

Base Information

• Chemical Name: methoxytriphenylstannane
• CAS No.: 1091-26-5
• Molecular Formula: C₁₉H₁₈OSn
• Molecular Weight: 381.061
• Mol file: 1091-26-5.mol

Synonyms:methoxytriphenylstannane

Chemical Property of methoxytriphenylstannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methoxytriphenylstannane

There total 3 articles about methoxytriphenylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.8%

triphenyltin chloride (639-58-7) → methoxytriphenylstannane (1091-26-5)

Guidance literature:

With methanol; n-butyl lithium; In methanol; hexane; byproducts: LiCl; Ar atmosphere; addn. of BuLi in hexane to soln. of Sn-compd. in MeOH (-30°C), stirring (30 min); evapn., addn. of C6H6, removal of LiCl on centrifugation, evapn., recrystn. (pentane); elem. anal.;

Reference yield:

dimethylamidotriphenyltin(IV) (1092-86-0) + Methyl isobutyrate (547-63-7,133320-07-7,67505-84-4) → methoxytriphenylstannane (1091-26-5)

Guidance literature:

With dimethylformamide; In benzene-d6; N,N-dimethyl-formamide; byproducts: (CH3)2CHCON(CH3)2; using Schlenk techniques; benzene-d6 soln. of Ph3SnNMe2 and Me2CHCOOMe in 1:1 ratio in the presence of 5 eq. DMF at 26°C; monitoring by NMR; Kinetics;

DOI:10.1039/b306700a

Reference yield:

dimethylamidotriphenyltin(IV) (1092-86-0) + methanol (67-56-1) → methoxytriphenylstannane (1091-26-5)

Guidance literature:

In methanol;

DOI:10.1039/b300101f

upstream raw materials:

dimethylamidotriphenyltin(IV)

Methyl isobutyrate

methanol

triphenyltin chloride

Downstream raw materials:

triphenylstannane

methyltriphenylstannylmercury

bis(trimethylsilyl)amino-trimethylsilylimino-methoxy-triphenylstannyl-phosphorane

α-(triphenylstannyl)acetophenone

Refernces

• 1、 Chisholm, Malcolm H.,Delbridge, Ewan E.. "A study of the ring-opening of lactides and related cyclic esters by Ph2SnX2 and Ph3SnX compounds (X = NMe 2, OR)". . p. 1167 - 1176. Retrieved 2007/10/03.