bis(trimethylsilyl)-p-chlorophenylphosphonate

Base Information

• Chemical Name: bis(trimethylsilyl)-p-chlorophenylphosphonate
• CAS No.: 104412-65-9
• Molecular Formula: C₁₂H₂₂ClO₃PSi₂
• Molecular Weight: 336.903
• Mol file: 104412-65-9.mol

Synonyms:bis(trimethylsilyl)-p-chlorophenylphosphonate

Chemical Property of bis(trimethylsilyl)-p-chlorophenylphosphonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(trimethylsilyl)-p-chlorophenylphosphonate

There total 1 articles about bis(trimethylsilyl)-p-chlorophenylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bromochlorobenzene (106-39-8) + tris(trimethylsilyl) phosphite (1795-31-9) → bis(trimethylsilyl)-p-chlorophenylphosphonate (104412-65-9)

Guidance literature:

With nickel dichloride; at 150 ℃; for 0.5h;

DOI:10.1007/BF00863831

Reference yield: 100.0%

bis(trimethylsilyl)-p-chlorophenylphosphonate (104412-65-9) → 4-chlorophenylphosphonic acid (5431-35-6)

Guidance literature:

With methanol; for 24h; Ambient temperature;

DOI:10.1007/BF00863831

upstream raw materials:

bromochlorobenzene

tris(trimethylsilyl) phosphite

Downstream raw materials:

4-chlorophenylphosphonic acid

Refernces

• 1、 Demik, N. N.,Kabachnik, M. M.,Novikova, Z. S.,Beletskaya, I. P.. "PREPARATION OF ARYLPHOSPHONATES BY THE REACTION OF ARYL HALIDES WITH TRIS(TRIMETHYLSILYL) PHOSPHITE UNDER HOMOGENEOUS CATALYSIS CONDITIONS". . p. 1300 - 1301. Retrieved 2007/10/02.