tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II)

Base Information

• Chemical Name: tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II)
• CAS No.: 87261-81-2
• Molecular Formula: C₄₄H₂₄CuN₄O₁₂S₄
• Molecular Weight: 992.504
• Mol file: 87261-81-2.mol

Synonyms:tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II)

Chemical Property of tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II)

There total 8 articles about tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphine(4-) + copper diacetate (142-71-2) → tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II) (87261-81-2)

Guidance literature:

In methanol; water; 10-fold execess Cu(OAc)2 was added to soln. tetra-(4-sufonatophenyl)porphine in 95:5 methanol/water, 12 h; acetone was added, ppt was filtered, washed with acetone and water;

DOI:10.1021/ja0317731

Reference yield:

mercury(II) 5,10,15,20-tetrakis(4-sulfonatophenyl)porphine complex + copper diacetate (142-71-2) → tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II) (87261-81-2)

Guidance literature:

With sodium hydroxide; sodium acetate; acetic acid; In water; byproducts: Hg(2+); in aq. acetate buffer soln. at pH 5.4; detected by EXAFS; Kinetics;

Reference yield:

tetrasodium 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin + copper dichloride → tetraanionic meso-tetrakis(4-sulfonatophenyl)porphyrincopper(II) (87261-81-2)

Guidance literature:

In water; excess of CuCl2 heated with porphine in dist. water on a steam bath for1 h; passing through cation exchanger column, soln. brought to a pH 6, volume reduced, acetone added, recrystd. three times from methanol;

DOI:10.1021/ja00531a042

upstream raw materials:

mercury(II) diacetate

copper diacetate

(N-methyltetrakis(p-sulfophenyl)porphinato)copper(II)^(3-)

diethylamine

Refernces

• 1、 Wei, Keke,Yao, Fujun,Kang, Xiao-Feng. "Single-molecule porphyrin-metal ion interaction and sensing application". . p. 272 - 278. Retrieved 2018.
• 2、 Torki, Farid M. El,Casano, Peter J.,Reed, Wayne F.,Schmehl, Russell H.. "Association of Small Molecule Cosolutes with Water-Soluble Polymers. Effects of Polymer Binding on the Reactivity of Water-Soluble Porphyrins". . p. 3686 - 3690. Retrieved 1987.
• 3、 Bandyopadhyay,Banerjea. "Kinetic Studies on Metalloporphyrin Formation in Aqueous Solutions of meso-Tetra(p-sulphonatophenyl)-porphyrin and some Metal(II) Ions". . p. 153 - 157. Retrieved 2007/10/03.