Dibromo(1,10-phenanthroline)copper(II)

Base Information

• Chemical Name: Dibromo(1,10-phenanthroline)copper(II)
• CAS No.: 19319-86-9
• Molecular Formula: C₁₂H₈Br₂CuN₂
• Molecular Weight: 403.563
• European Community (EC) Number: 623-675-9
• DSSTox Substance ID: DTXSID80421996
• Mol file: 19319-86-9.mol

Synonyms:Dibromo(1,10-phenanthroline)copper(II);19319-86-9;dibromocopper;1,10-phenanthroline;SCHEMBL343946;DTXSID80421996;SC10075;dibromo(1,10-phenanthroli-ne)copper(ii);DIBROMO(1,10-PHENANTHROLINE) COPPER(II);DIBROMIDO(1,10-PHENANTHROLINE)COPPER(II)

Chemical Property of Dibromo(1,10-phenanthroline)copper(II)

Chemical Property:

• Vapor Pressure: 3.38E-05mmHg at 25°C
• Melting Point: 280 °C (dec.)(lit.)
• Boiling Point: 365.1°C at 760 mmHg
• Flash Point: 164.8°C
• PSA: 25.78000
• LogP: -3.21150
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 402.83297
• Heavy Atom Count: 17
• Complexity: 185

Purity/Quality:

98%Min ^*data from raw suppliers

DIBROMO(1,10-PHENANTHROLINE)COPPER(II) 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[Cu](Br)Br

Technology Process of Dibromo(1,10-phenanthroline)copper(II)

There total 2 articles about Dibromo(1,10-phenanthroline)copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

1,10-phenanthroline hydrate (5144-89-8) + copper(ll) bromide (7789-45-9) → dibromo(1,10-phenanthroline)copper(II) (19319-86-9,29932-22-7)

Guidance literature:

With CuI; In water; High Pressure; a mixt. of CuI, CuBr2, phenanthroline and H2O in a molar ratio 1:2:1.5:400 was stirred and heated at 160°C for 4 days under autogenous pressure; crystals were filtered, washed with distilled water and dried in air at ambient temp.; elem. anal.;

DOI:10.1039/b314974a

Reference yield:

1,10-Phenanthroline (66-71-7) + copper(ll) bromide (7789-45-9) → dibromo(1,10-phenanthroline)copper(II) (19319-86-9,29932-22-7)

Guidance literature:

In ethanol; react. mixt. refluxed, microcryst. solid formed upon cooling; recrystd. from hot dimethylacetamide;

upstream raw materials:

1,10-Phenanthroline

copper(ll) bromide

1,10-phenanthroline hydrate

Refernces

• 1、 Yu, Jie-Hui,Lue, Zheng-Liang,Xu, Ji-Qing,Bie, Hai-Ying,Lu, Jing,Zhang, Xiao. "Syntheses, characterization and optical properties of some copper(I) halides with 1,10-phenanthroline ligand". . p. 940 - 945. Retrieved 2007/10/03.