5-Hexenyltrichlorosilane

Base Information

• Chemical Name: 5-Hexenyltrichlorosilane
• CAS No.: 18817-29-3
• Molecular Formula: C6H11Cl3Si
• Molecular Weight: 217.598
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID80446088
• Nikkaji Number: J364.495B
• Wikidata: Q82264660
• Mol file: 18817-29-3.mol

Synonyms:18817-29-3;5-HEXENYLTRICHLOROSILANE;Trichloro(hex-5-enyl)silane;trichloro(hex-5-en-1-yl)silane;Silane, trichloro-5-hexen-1-yl-;5-Hexenyltrichlorosilane,95%;5-Hexenyltrichlorosilane 95%;Silane, trichloro-5-hexenyl-;6-hex-1-enyltrichlorosilane;SCHEMBL388118;DTXSID80446088;IHYCWJYGNRZAOB-UHFFFAOYSA-N;MFCD00054834;5-HEXENYLTRICHLOROSILANE, 95%?

Chemical Property of 5-Hexenyltrichlorosilane

Chemical Property:

• Appearance/Colour: 2987
• Vapor Pressure: 0.556mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.461
• Boiling Point: 33-4°C 0,7mm
• Flash Point: 60°C
• PSA: 0.00000
• Density: 1.13 g/cm³
• LogP: 3.99800
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 215.969560
• Heavy Atom Count: 10
• Complexity: 97.7

Purity/Quality:

98% ^*data from raw suppliers

5-HEXENYLTRICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34-36/37/38
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCC[Si](Cl)(Cl)Cl

Technology Process of 5-Hexenyltrichlorosilane

There total 11 articles about 5-Hexenyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,5-Hexadien (592-42-7) → 5-hexenyltrichlorosilane (18817-29-3)

Guidance literature:

With trichlorosilane; platinum;

Reference yield: 50.0%

6-Bromo-1-hexene (2695-47-8) → 5-hexenyltrichlorosilane (18817-29-3)

Guidance literature:

With tetrachlorosilane; magnesium; ethylene dibromide; In diethyl ether;

DOI:10.1021/ja057947r

Reference yield:

1 ,6-dibromohexane (629-03-8) → 5-hexenyltrichlorosilane (18817-29-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 50 percent / KOH; 18-crown-6 ether / various solvent(s) / 1 h / 250 °C / 100 Torr

2: 50 percent / Mg; SiCl₄ / 1,2-dibromoethane / diethyl ether

With potassium hydroxide; tetrachlorosilane; 18-crown-6 ether; magnesium; ethylene dibromide; In diethyl ether;

DOI:10.1021/ja0675292

upstream raw materials:

1,5-Hexadien

trichlorosilane

6-Bromo-1-hexene

1 ,6-dibromohexane

Downstream raw materials:

n-5-hexenylsilane

tri(9-carbazole)ethoxy-5-hexenylsilane

Refernces

• 1、 Amin, Smruti B.,Marks, Tobin J.. "Alkenylsilane structure effects on mononuclear and binuclear organotitanium-mediated ethylene polymerization: Scope and mechanism of simultaneous polyolefin branch and functional group introduction". . p. 2938 - 2953. Retrieved 2007/10/03.
• 2、 -. "PREPARATION OF A HALOSILYLATED CHAIN HYDROCARBON". Page/Page column 17; 19. . Retrieved 2008/06/13.