(diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone)

Base Information

• Chemical Name: (diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone)
• CAS No.: 1392603-27-8
• Molecular Formula: C₈Cl₂N₂O₂*C₁₈H₁₉O₇P
• Molecular Weight: 605.325
• Mol file: 1392603-27-8.mol

Synonyms:(diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone)

Chemical Property of (diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone)

There total 7 articles about (diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

(3,6-dihydroxy-9H-xanthen-9-yl)methyl diethyl phosphate (1392603-22-3) + 2,3-dicyano-5,6-dichloro-p-benzoquinone (84-58-2) → (diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone) (1392603-27-8)

Guidance literature:

In acetonitrile; at 20 ℃; for 0.333333h;

DOI:10.1021/jo301455n

Reference yield:

(3,6-dimethoxy-9H-xanthen-9-yl)methyl diethyl phosphate (1392603-19-8) → (diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone) (1392603-27-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: boron tribromide / dichloromethane / 24 h / -78 - -10 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: acetonitrile / 0.33 h / 20 °C

With boron tribromide; In dichloromethane; acetonitrile;

DOI:10.1021/jo301455n

Reference yield:

2,2',4,4'-tetrahydroxybenzophenone (131-55-5) → (diethyl (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl phosphate)*(2,3-dichloro-5,6-dicyano-1,4-benzoquinone) (1392603-27-8)

Guidance literature:

Multi-step reaction with 7 steps

1.1: water / 6 h / 200 °C / Autoclave

2.1: potassium carbonate / acetone / 20 h / Reflux

3.1: benzene; toluene / 25 - 65 °C / Inert atmosphere

3.2: 0 °C / Inert atmosphere

4.1: borane-THF / tetrahydrofuran / 0 - 20 °C

4.2: 0 - 20 °C

4.3: pH 7

5.1: dmap / dichloromethane / 24 h / 20 °C / Inert atmosphere

6.1: boron tribromide / dichloromethane / 24 h / -78 - -10 °C / Inert atmosphere

6.2: Inert atmosphere

7.1: acetonitrile / 0.33 h / 20 °C

With dmap; borane-THF; boron tribromide; potassium carbonate; In tetrahydrofuran; dichloromethane; water; acetone; toluene; acetonitrile; benzene;

DOI:10.1021/jo301455n

upstream raw materials:

(3,6-dimethoxy-9H-xanthen-9-yl)methanol

(3,6-dimethoxy-9H-xanthen-9-yl)methyl diethyl phosphate

(3,6-dihydroxy-9H-xanthen-9-yl)methyl diethyl phosphate

2,3-dicyano-5,6-dichloro-p-benzoquinone

Downstream raw materials:

3,6-dihydroxy-xanthen-9-one

Diethyl phosphate

Refernces