Carbonic acid, p-methoxyphenyl phenyl ester

Base Information

• Chemical Name: Carbonic acid, p-methoxyphenyl phenyl ester
• CAS No.: 17145-95-8
• Molecular Formula: C14H12 O4
• Molecular Weight: 244.247
• Hs Code.: 2920909090
• DSSTox Substance ID: DTXSID701263725
• Nikkaji Number: J142.124G
• Mol file: 17145-95-8.mol

Synonyms:(4-methoxyphenyl) phenyl carbonate;Carbonic acid, p-methoxyphenyl phenyl ester;Carbonic acid, 4-methoxyphenyl phenyl ester;17145-95-8;SCHEMBL5696756;p-Methoxyphenyl phenyl carbonate;DTXSID701263725;4-Methoxyphenyl phenyl carbonate #;Carbonic acid 4-methoxyphenylphenyl ester

Chemical Property of Carbonic acid, p-methoxyphenyl phenyl ester

Chemical Property:

• Boiling Point: 348.8±25.0 °C(Predicted)
• PSA: 44.76000
• Density: 1.203±0.06 g/cm3(Predicted)
• LogP: 3.27300
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 244.07355886
• Heavy Atom Count: 18
• Complexity: 253

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)OC(=O)OC2=CC=CC=C2

Technology Process of Carbonic acid, p-methoxyphenyl phenyl ester

There total 11 articles about Carbonic acid, p-methoxyphenyl phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

phenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate (1202680-24-7) + 4-methoxy-phenol (150-76-5) → 4-methoxyphenyl phenyl carbonate (17145-95-8)

Guidance literature:

With aluminum (III) chloride; In toluene; at 20 ℃; for 2h;

DOI:10.5012/bkcs.2014.35.9.2758

Reference yield: 38.0%

dimethyl acetylenedicarboxylate (762-42-5) + 2-(p-methoxyphenoxy)-2-phenoxy-5,5-dimethyl-Δ3-1,3,4-oxadiazoline (351197-68-7) → 4-methoxyphenyl phenyl carbonate (17145-95-8) + (E)-2-Methoxycarbonyl-3-phenyl-but-2-enedioic acid 1-(4-methoxy-phenyl) ester 4-methyl ester

Guidance literature:

In benzene; at 110 ℃;

DOI:10.1139/v01-029

Reference yield:

phenyl O‐(4‐nitrophenyl) carbonate (17175-11-0) + 4-methoxy-phenol (150-76-5) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 4-methoxyphenyl phenyl carbonate (17145-95-8)

Guidance literature:

With potassium chloride; In water; at 25 ℃; pH=10.0; Further Variations:; pH-values; Kinetics;

DOI:10.1039/b103397m

upstream raw materials:

dimethyl acetylenedicarboxylate

2-(p-methoxyphenoxy)-2-phenoxy-5,5-dimethyl-Δ³-1,3,4-oxadiazoline

phenyl 2,4-dinitrophenyl carbonate

4-methoxy-phenol

Refernces

• 1、 Sung, Gi Hyeon,Bo, Ram Kim,Ryu, Ki Eun,Kim, Jeum-Jong,Yoon, Yong-Jin. "Synthesis of organic carbonates with alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates and ROH/AlCl3under ambient condition". . p. 2758 - 2764. Retrieved 2015/04/22.
• 2、 Lu,Reid,Warkentin. "Diaryloxycarbenes from oxadiazolines". . p. 319 - 327. Retrieved 2007/10/03.