chloro(4-(methylthio)phenyl)dimethylsilane

Base Information

• Chemical Name: chloro(4-(methylthio)phenyl)dimethylsilane
• CAS No.: 1166892-09-6
• Molecular Formula: C₉H₁₃ClSSi
• Molecular Weight: 216.807
• Mol file: 1166892-09-6.mol

Synonyms:chloro(4-(methylthio)phenyl)dimethylsilane

Chemical Property of chloro(4-(methylthio)phenyl)dimethylsilane

Chemical Property:

Purity/Quality:

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Technology Process of chloro(4-(methylthio)phenyl)dimethylsilane

There total 1 articles about chloro(4-(methylthio)phenyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

(4-bromophenyl)thioanisole (104-95-0) + dimethylsilicon dichloride (75-78-5,30107-43-8) → chloro(4-(methylthio)phenyl)dimethylsilane (1166892-09-6)

Guidance literature:

(4-bromophenyl)thioanisole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2.5h; Schlenk technique;

dimethylsilicon dichloride; In tetrahydrofuran; hexane; at -78 - 20 ℃; Schlenk technique;

DOI:10.1021/ja410656a

Reference yield: 80.0%

chloro(4-(methylthio)phenyl)dimethylsilane (1166892-09-6) → 1,1'-oxybis(1-(4-(methylthio)phenyl))dimethylsilane (1379575-47-9)

Guidance literature:

With water; triethylamine; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1021/ja410656a

upstream raw materials:

(4-bromophenyl)thioanisole

dimethylsilicon dichloride

Downstream raw materials:

1,1'-oxybis(1-(4-(methylthio)phenyl))dimethylsilane

Refernces