Myristic acid, [1-14C]

Base Information

• Chemical Name: Myristic acid, [1-14C]
• CAS No.: 17029-30-0
• Molecular Formula: C₁₄H₂₈O₂
• Molecular Weight: 230.364
• DSSTox Substance ID: DTXSID001313228
• Mol file: 17029-30-0.mol

Synonyms:17029-30-0;MYRISTIC ACID, [1-14C];(114C)tetradecanoic acid;Myristic acid-carboxy-14C;Myristic acid,[1-14c];Tetradecanoic-1-14C acid;SCHEMBL10824324;DTXSID001313228

Chemical Property of Myristic acid, [1-14C]

Chemical Property:

• PSA: 37.30000
• LogP: 4.77210
• Storage Temp.: 2-8°C
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 230.21217212
• Heavy Atom Count: 16
• Complexity: 155

Purity/Quality:

98% ^*data from raw suppliers

MYRISTIC ACID[1-14C] 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 36/37/38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC(=O)O
• Isomeric SMILES: CCCCCCCCCCCCC[14C](=O)O

Technology Process of Myristic acid, [1-14C]

There total 4 articles about Myristic acid, [1-14C] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

1-(14)-1-tetradecanenitrile → [1-14C]myristic acid (17029-30-0)

Guidance literature:

With hydrogenchloride; water; for 12h; Reflux;

DOI:10.1002/jlcr.1762

Reference yield:

1-bromotridecane (765-09-3) → [1-14C]myristic acid (17029-30-0)

Guidance literature:

Multi-step reaction with 2 steps

1: N,N-dimethyl-formamide / 2 h / Reflux

2: hydrogenchloride; water / 12 h / Reflux

With hydrogenchloride; water; In N,N-dimethyl-formamide;

DOI:10.1002/jlcr.1762

Reference yield:

n-tetradecanoic acid (544-63-8) → [1-14C]myristic acid (17029-30-0)

Guidance literature:

Multi-step reaction with 4 steps

1: oxalyl dichloride; N,N-dimethyl-formamide

2: dmap; Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt / 4 h / Reflux

3: N,N-dimethyl-formamide / 2 h / Reflux

4: hydrogenchloride; water / 12 h / Reflux

With hydrogenchloride; dmap; oxalyl dichloride; Bromotrichloromethane; water; 2-mercaptopyridine-1-oxide sodium salt; N,N-dimethyl-formamide; In N,N-dimethyl-formamide; 2: Hunsdiecker-Borodin reaction;

DOI:10.1002/jlcr.1762

upstream raw materials:

1-bromotridecane

n-tetradecanoic acid

tetradecanoyl chloride

Refernces