Phosphorodithioic acid, O,O-dimethyl ester, potassium salt (1:1)

Base Information

• Chemical Name: Phosphorodithioic acid, O,O-dimethyl ester, potassium salt (1:1)
• CAS No.: 16001-68-6
• Molecular Formula: C2H7 O2 P S2 . K
• Molecular Weight: 196.273
• DSSTox Substance ID: DTXSID90166785
• Wikidata: Q26840741
• Mol file: 16001-68-6.mol

Synonyms:16001-68-6;Phosphorodithioic acid, O,O-dimethyl ester, potassium salt (1:1);potassium;dimethoxy-sulfanylidene-sulfido-lambda5-phosphane;potassium O,O-dimethyl phosphorodithioate;Phosphorodithioic acid, O,O-dimethyl ester, potassium salt;SCHEMBL11799655;DTXSID90166785;AKOS030508089;AM84935;dimethoxy-sulfanylidene-sulfidophosphorane;Q26840741

Chemical Property of Phosphorodithioic acid, O,O-dimethyl ester, potassium salt (1:1)

Chemical Property:

• Boiling Point: 194.1°Cat760mmHg
• Flash Point: 71.2°C
• PSA: 60.36000
• Density: 1.314g/cm³
• LogP: 1.70120
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 195.91839026
• Heavy Atom Count: 8
• Complexity: 90

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COP(=S)(OC)[S-].[K+]

Technology Process of Phosphorodithioic acid, O,O-dimethyl ester, potassium salt (1:1)

There total 2 articles about Phosphorodithioic acid, O,O-dimethyl ester, potassium salt (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) → potassium O,O-dimethyldithiophosphate (16001-68-6)

Guidance literature:

With tetraphosphorus decasulfide; potassium carbonate; at 60 ℃; for 2h;

Reference yield:

→ potassium O,O-dimethyldithiophosphate (16001-68-6)

Guidance literature:

Reference yield: 85.0%

phenyl(phenylethynyl)iodonium tosylate (79069-32-2) + potassium O,O-dimethyldithiophosphate (16001-68-6) → O,O-Dimethyl-S-phenylethinyldithiophosphat (94783-75-2)

Guidance literature:

With N-benzyl-N,N,N-triethylammonium chloride; In chloroform; water; for 0.333333h; Ambient temperature;

DOI:10.1021/jo00059a053

upstream raw materials:

methanol

Downstream raw materials:

Dimethoate

(dimethoxythiophosphorylsulfanyl-acetyl)-urea

dithiophosphoric acid O,O'-dimethyl ester-S-(3-phenyl-propyl ester)

(dimethoxythiophosphinoylmercapto)benzene

Refernces