2-CHLOROBENZOIC ACID VINYL ESTER

Base Information

• Chemical Name: 2-CHLOROBENZOIC ACID VINYL ESTER
• CAS No.: 15721-27-4
• Molecular Formula: C9H7 Cl O2
• Molecular Weight: 182.6
• Hs Code.: 2916399090
• Mol file: 15721-27-4.mol

Synonyms:Benzoicacid, o-chloro-, vinyl ester (7CI,8CI); Vinyl o-chlorobenzoate

Chemical Property of 2-CHLOROBENZOIC ACID VINYL ESTER

Chemical Property:

• Refractive Index: 1.5450-1.5470
• Boiling Point: 130 °C / 16mmHg
• Flash Point: 126.9oC
• PSA: 26.30000
• Density: 1.22
• LogP: 2.64030

Purity/Quality:

98%,99%, ^*data from raw suppliers

Vinyl2-Chlorobenzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-CHLOROBENZOIC ACID VINYL ESTER

There total 2 articles about 2-CHLOROBENZOIC ACID VINYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vinyl acetate (108-05-4,9003-20-7) + ortho-chlorobenzoic acid (118-91-2) → 2-chlorobenzoic acid vinyl ester (15721-27-4)

Guidance literature:

With rhodium(III) chloride trihydrate; sodium formate; at 80 ℃; for 24h;

DOI:10.1016/j.tetlet.2018.07.039

Reference yield:

acetylene (74-86-2,25067-58-7) + ortho-chlorobenzoic acid (118-91-2) → 2-chlorobenzoic acid vinyl ester (15721-27-4)

Guidance literature:

With acetic anhydride; toluene; zinc(II) oxide; at 230 ℃;

DOI:10.1002/macp.1956.020180121

Reference yield:

tertiary butyl chloride (507-20-0) + 2-chlorobenzoic acid vinyl ester (15721-27-4) → C13H16Cl2O2

Guidance literature:

tertiary butyl chloride; In 1,2-dichloro-ethane; at -8 ℃; for 1h; Inert atmosphere;

2-chlorobenzoic acid vinyl ester; In 1,2-dichloro-ethane; for 3h; Inert atmosphere;

upstream raw materials:

acetylene

ortho-chlorobenzoic acid

vinyl acetate

Refernces