N-PROPYLDICHLOROPHOSPHINE

Base Information

• Chemical Name: N-PROPYLDICHLOROPHOSPHINE
• CAS No.: 15573-31-6
• Molecular Formula: C3H7 Cl2 P
• Molecular Weight: 144.968
• Mol file: 15573-31-6.mol

Synonyms:Phosphonousdichloride, propyl- (6CI,7CI,8CI,9CI); Dichloropropylphosphine;Propyldichlorophosphine

Chemical Property of N-PROPYLDICHLOROPHOSPHINE

Chemical Property:

• Vapor Pressure: 8.79mmHg at 25°C
• Melting Point: 135-136℃
• Boiling Point: 137.3°Cat760mmHg
• Flash Point: 36.8°C
• PSA: 13.59000
• Density: g/cm³
• LogP: 3.18590
• Sensitive.: Air & Moisture Sensitive

Purity/Quality:

99% ^*data from raw suppliers

n-Propyldichlorophosphine, min. 98% ^*data from reagent suppliers

Safty Information:

• Statements: 14-34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-PROPYLDICHLOROPHOSPHINE

There total 5 articles about N-PROPYLDICHLOROPHOSPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

1-propylmagnesium chloride (2234-82-4) → dichloropropylphosphine (15573-31-6)

Guidance literature:

With zinc(II) chloride; phosphorus trichloride; In diethyl ether; for 1.16667h; Heating;

DOI:10.1039/b006883g

Reference yield:

n-propylmagnesium bromide (927-77-5) → dichloropropylphosphine (15573-31-6)

Guidance literature:

With diethyl ether; cadmium(II) chloride; und anschliessend PCl₃;

DOI:10.1021/ja01165a085

Reference yield:

di-n-propylmercury (628-85-3) → dichloropropylphosphine (15573-31-6)

Guidance literature:

With phosphorus trichloride; at 250 ℃;

upstream raw materials:

tri-n-propylamine

n-propylmagnesium bromide

di-n-propylmercury

1-propylmagnesium chloride

Downstream raw materials:

Propanthiophosphonsaeuredichlorid

P₂(C₃H₇)2(P(C₆H₅)2C₆H₄)2⁽²⁺⁾*SnCl₆^(2-)=(C₃H₇)2P₂(P(C₆H₅)2C₆H₄)2SnCl₆

P₂(CH₂CH₂CH₃)2CH₂P₂(C₆H₅)4⁽²⁺⁾*SnCl₆^(2-)=P₂(C₃H₇)2CH₂P₂(C₆H₅)4(SnCl₆)

P₂(C₃H₇)2CH₂P₂(C₆H₁₁)4⁽²⁺⁾*SnCl₆^(2-)=P₂(C₃H₇)2CH₂P₂(C₆H₁₁)4(SnCl₆)

Refernces