Z-7-DECEN-1-YL ACETATE

Base Information

• Chemical Name: Z-7-DECEN-1-YL ACETATE
• CAS No.: 13857-03-9
• Molecular Formula: C₁₂H₂₂O₂
• Molecular Weight: 198.305
• Hs Code.: 2915390090
• Mol file: 13857-03-9.mol

Synonyms:7-Decen-1-ol,acetate, (7Z)- (9CI); 7-Decen-1-ol, acetate, (Z)- (8CI); (Z)-7-Decenyl acetate;cis-7-Decen-1-yl acetate; cis-7-Decenyl acetate

Chemical Property of Z-7-DECEN-1-YL ACETATE

Chemical Property:

• Vapor Pressure: 0.00967mmHg at 25°C
• Refractive Index: 1.444
• Boiling Point: 264.5±19.0℃ (760 Torr)
• Flash Point: 92.4±19.9℃
• PSA: 26.30000
• Density: 0.886±0.06 g/cm3 (20 ºC 760 Torr)
• LogP: 3.46620

Purity/Quality:

93% ^*data from raw suppliers

Z-7-Decen-1-ylacetate 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Z-7-DECEN-1-YL ACETATE

There total 11 articles about Z-7-DECEN-1-YL ACETATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

Dec-7-in-1-yl acetat (13857-02-8) → (Z)-7-decenyl acetate (13857-03-9)

Guidance literature:

With quinoline; hydrogen; Lindlar's catalyst; In ethanol;

DOI:10.1080/00397919508011480

Reference yield:

1-(2-Tetrahydropyranyloxy)-7-octyne (16695-31-1) → (Z)-7-decenyl acetate (13857-03-9)

Guidance literature:

Multi-step reaction with 4 steps

1: 1.) LiNH₂, liq. NH₃, HMPA / 1.) -33 deg C, 2 h, 2.) THF, -33 deg C, 6 h

2: 90 percent / PTSA / methanol; H₂O / 12 h / Ambient temperature

3: 88.8 percent / DMAP / pyridine / 8 h / Ambient temperature

4: 85 percent / H₂, quinoline / Lindlar catalyst / ethanol

With quinoline; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; lithium amide; ammonia; hydrogen; toluene-4-sulfonic acid; Lindlar's catalyst; In pyridine; methanol; ethanol; water;

DOI:10.1080/00397919508011480

Reference yield:

7-decyn-1-ol (69222-08-8) → (Z)-7-decenyl acetate (13857-03-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 88.8 percent / DMAP / pyridine / 8 h / Ambient temperature

2: 85 percent / H₂, quinoline / Lindlar catalyst / ethanol

With quinoline; dmap; hydrogen; Lindlar's catalyst; In pyridine; ethanol;

DOI:10.1080/00397919508011480

upstream raw materials:

Dec-7-in-1-yl acetat

1-(2-Tetrahydropyranyloxy)-7-octyne

7-decyn-1-ol

4-octyne-1-ol

Refernces

• 1、 -. "PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS". Paragraph 0386; 0402. . Retrieved 2017/06/12.