Technology Process of [Pd(C,N-κ2-C6H4CH=NC6H3-2,6-i-Pr2)(μ-Cl)]2
There total 5 articles about [Pd(C,N-κ2-C6H4CH=NC6H3-2,6-i-Pr2)(μ-Cl)]2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
NaCH3COO;
In
methanol;
inert atmosphere using standard Schlenk techniques; soln. of Na2PdCl2, ligand and NaOAc (1:2:2 mol) stirred at room temp. for 6 h; product filtered off; washed (H2O, Et2O); dissolved in CH2Cl2; soln. filtered; filtrate evapd.; residue crystd. (CH2Cl2/hexane); elem. anal.;
DOI:10.1016/j.ica.2011.06.003
- Guidance literature:
-
With
sodium acetate;
In
dichloromethane;
(N2); using Schlenk techniques; addn. of benzylidene-2,6-diisopropylphenylamine (1 equiv.) and NaOAc (2 equiv.) to stirring soln. of (MeCN)2PdCl2 (1 equiv.) in CH2Cl2, stirring for 18 h at room temp.; removal of solvent, redissolving in CH2Cl2, filtration, removal of solvent from filtrate, recrystn. from CH2Cl2:hexane;
DOI:10.1016/j.jorganchem.2011.07.044
- Guidance literature:
-
With
sodium acetate;
In
tetrahydrofuran;
under N2; pre-dried MeCN added to PdCl2; stirred at room temp. for 2 d; solvent removed to dryness; ligand (1.06 equiv.), Na acetate (15.5 equiv.) and THF added; stirred at room temp. for 38 h; solvent removed; CH2Cl2 added; filtered through Celite; filtrate concd.;washed with hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2004.03.002
