bis(triphenylphosphine)iminium tetrasulfur pentanitride

Base Information

• Chemical Name: bis(triphenylphosphine)iminium tetrasulfur pentanitride
• CAS No.: 72884-88-9
• Molecular Formula: C₃₆H₃₀NP₂*N₅S₄
• Molecular Weight: 736.886
• Mol file: 72884-88-9.mol

Synonyms:bis(triphenylphosphine)iminium tetrasulfur pentanitride

Chemical Property of bis(triphenylphosphine)iminium tetrasulfur pentanitride

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)iminium tetrasulfur pentanitride

There total 4 articles about bis(triphenylphosphine)iminium tetrasulfur pentanitride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bis(triphenylphosphine)iminium chloride (21050-13-5) + piperidinium tetrasulfur pentanitride → bis(triphenylphosphine)iminium tetrasulfur pentanitride (72884-88-9)

Guidance literature:

In water;

DOI:10.1021/ja00538a013

Reference yield: 42.0%

bis(triphenylphosphine)iminium trisulfur trinitride → ((C6H5)3P)2N(1+)*S3N3O(1-)=(((C6H5)3P)2N)S3N3O (81260-54-0) + ((C6H5)3P)2N(1+)*S4N5O(1-)=(((C6H5)3P)2N)S4N5O (86163-11-3) + bis(triphenylphosphine)iminium tetrasulfur pentanitride (72884-88-9)

Guidance literature:

With O₂; In acetonitrile; O2 bubbled into stirred (((C6H5)3P)2N)S3N3 soln. for 30 min, left to stand for 1 h; concd. (vac.), warmed, cooled to -20°C overnight, crystals manually sepd., recrystd. (MeCN); elem. anal.;

Reference yield: 19.0%

bis(triphenylphosphine)iminium trisulfur trinitride → N(P(C6H5)3)2(1+)*S4N5(1-)=[N(P(C6H5)3)2][S4N5] (72884-88-9) + tetrasulfur tetranitride (28950-34-7)

Guidance literature:

With (Bu₄N)BF₄; In dichloromethane; Electrochem. Process; potentiostatic oxidn. under Ar or N2; extn., chromy., recrystn. (acetonitrile);

upstream raw materials:

bis(triphenylphosphine)iminium chloride

Refernces

• 1、 Chivers, Tristram,Cordes, A. Wallace,Oakley, Richard T.,Pennington, William T.. "15N NMR study of the oxidation of the trisulfur trinitride anion by molecular oxygen: A comparison of the molecular and electronic structures of the S3N3-, S3N3O-, and S3N3O2- ions". . p. 2429 - 2435. Retrieved 2008/10/08.